Charge-Compensating Defect in Ceria-Doped Strontium Barium Niobate by Electron Energy-Loss Spectroscopy and X-ray Photoelectron Spectroscopy
作者： Jyh-Tzong Shiue , Tsang-Tse Fang
DOI: 10.1111/J.1551-2916.2004.00391.X
关键词: Doping 、 Valence (chemistry) 、 Chemistry 、 Strontium barium niobate 、 Analytical chemistry 、 X-ray photoelectron spectroscopy 、 Binding energy 、 Cerium 、 Spectroscopy 、 Electron energy loss spectroscopy 、 Mineralogy
摘要: Undoped and CeO2-doped Sr0.5Ba0.5Nb2O6 (SBN) powders were synthesized using the solid-state reaction method. The lattice parameters of undoped SBN evaluated X-ray diffractometry. valence state cerium ion in Ce-doped was identified photoelectron spectroscopy (XPS), 3+ confirmed. charge-compensated defect doping ceramics, i.e., excessive oxygen ions occupying vacant O(4) or O(5) site, further evidenced electron energy-loss (EELS) XPS. relationships defect, structure, binding energy, temperature maximum relative permittivity (Tm) discussed.
sci-hub.se 参考文章(29)
Ming-Hua Li, Tow-Chong Chong, Xue-Wu Xu, Hirohiko Kumagai, Structural and dielectric investigation of doped Sr0.61Ba0.39Nb2O6 crystals Journal of Applied Physics. ,vol. 89, pp. 5644- 5646 ,(2001) , 10.1063/1.1363686
I. A. Santos, D. U. Spı́nola, D. Garcia, J. A. Eiras, Dielectric behavior and diffuse phase transition features of rare earth doped Sr0.61Ba0.39Nb2O6 ferroelectric ceramics Journal of Applied Physics. ,vol. 92, pp. 3251- 3256 ,(2002) , 10.1063/1.1481210
P. Lehnen, W. Kleemann, Th. Woike, R. Pankrath, Ferroelectric nanodomains in the uniaxial relaxor systemSr0.61−xBa0.39Nb2O6:Cex3+ Physical Review B. ,vol. 64, pp. 224109- ,(2001) , 10.1103/PHYSREVB.64.224109
Yu-Guo Wang, Wolfgang Kleemann, Theo Woike, Rainer Pankrath, Atomic force microscopy of domains and volume holograms in Sr 0.61 Ba 0.39 Nb 2 O 6 : C e 3 + Physical Review B. ,vol. 61, pp. 3333- 3336 ,(2000) , 10.1103/PHYSREVB.61.3333
W. Kleemann, J. Dec, S. Miga, Th. Woike, R. Pankrath, Non-Debye domain-wall-induced dielectric response inSr0.61−xCexBa0.39Nb2O6 Physical Review B. ,vol. 65, pp. 220101- ,(2002) , 10.1103/PHYSREVB.65.220101
T. Granzow, U. Dörfler, Th. Woike, M. Wöhlecke, R. Pankrath, M. Imlau, W. Kleemann, Influence of pinning effects on the ferroelectric hysteresis in cerium-doped Sr 0.61 Ba 0.39 Nb 2 O 6 Physical Review B. ,vol. 63, pp. 174101- ,(2001) , 10.1103/PHYSREVB.63.174101
Concetto R. Giuliano, Applications of optical phase conjugation Physics Today. ,vol. 34, pp. 27- 35 ,(1981) , 10.1063/1.2914508
Jyh-Tzong Shiue, Tsang-Tse Fang, The sintering behavior of CeO2-doped strontium barium niobate ceramics Journal of The European Ceramic Society. ,vol. 22, pp. 1705- 1709 ,(2002) , 10.1016/S0955-2219(01)00476-9
R. Niemann, K. Buse, R. Pankrath, M. Neumann, XPS study of photorefractive Sr0.61Ba0.39Nb2O6:Ce crystals Solid State Communications. ,vol. 98, pp. 209- 213 ,(1996) , 10.1016/0038-1098(96)00087-7
K. Megumi, H. Kozuka, M. Kobayashi, Y. Furuhata, High‐sensitive holographic storage in Ce‐doped SBN Applied Physics Letters. ,vol. 30, pp. 631- 633 ,(1977) , 10.1063/1.89287