Applicability of Augis–Bennett relation for determination of activation energy of glass transition in some Se rich chalcogenide glasses
作者： Shipra Saraswat , Neeraj Mehta , Surendra Dutt Sharma
DOI: 10.1016/J.JMRT.2015.07.002
关键词: Ternary operation 、 Materials science 、 Amorphous solid 、 Thermodynamics 、 Mineralogy 、 Thermal relaxation 、 Chalcogenide 、 Activation energy 、 Work (thermodynamics) 、 Phase transition 、 Glass transition
摘要: Abstract The present work reports the results of non-isothermal DSC measurements on some Se-based ternary glasses for evaluation activation glass transition. energy transition ( E g ) is determined using Augis–Bennett's relation, which basically derived amorphous to crystalline phase Moynihan's relation concept thermal relaxation and used also determination values. We have observed that values obtained from are in admirable agreement with relation.
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Deepika , Kuldeep Singh Rathore, Narendra Sahai Saxena, Kinetics of Phase Transformations and Thermal Stability of Se 58 Ge 42-x Pb x (x = 15, 18 & 20) Glasses New Journal of Glass and Ceramics. ,vol. 2012, pp. 23- 33 ,(2012) , 10.4236/NJGC.2012.21005
Boris V. L’vov, Activation effect in heterogeneous decomposition reactions: fact or fiction? Reaction Kinetics, Mechanisms and Catalysis. ,vol. 111, pp. 415- 429 ,(2014) , 10.1007/S11144-014-0675-5
C. A. Angell, K. L. Ngai, G. B. McKenna, P. F. McMillan, S. W. Martin, Relaxation in glassforming liquids and amorphous solids Journal of Applied Physics. ,vol. 88, pp. 3113- 3157 ,(2000) , 10.1063/1.1286035
A Zakery, S.R Elliott, Optical properties and applications of chalcogenide glasses: a review Journal of Non-crystalline Solids. ,vol. 330, pp. 1- 12 ,(2003) , 10.1016/J.JNONCRYSOL.2003.08.064
F.A. Al-Agel, Shamshad A. Khan, E.A. Al-Arfaj, A.A. Al-Ghamdi, Kinetics of non-isothermal crystallization and glass transition phenomena in Ga10Se87Pb3 and Ga10Se84Pb6 chalcogenide glasses by DSC Journal of Non-crystalline Solids. ,vol. 358, pp. 564- 570 ,(2012) , 10.1016/J.JNONCRYSOL.2011.10.029
Cornelius T. Moynihan, Allan J. Easteal, James Wilder, Joseph Tucker, Dependence of the glass transition temperature on heating and cooling rate The Journal of Physical Chemistry. ,vol. 78, pp. 2673- 2677 ,(1974) , 10.1021/J100619A008
Joachim Gottsmann, Andrew J.L. Harris, Donald B. Dingwell, Thermal history of Hawaiian pāhoehoe lava crusts at the glass transition: implications for flow rheology and emplacement Earth and Planetary Science Letters. ,vol. 228, pp. 343- 353 ,(2004) , 10.1016/J.EPSL.2004.09.038
Balbir Singh Patial, Nagesh Thakura, S. K. Tripathi, Kinetics of glass transition phenomenon of amorphous tin-based Se-Te semiconducting alloy SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. ,vol. 1447, pp. 589- 590 ,(2012) , 10.1063/1.4710141
P.E Viollaz, S.M Alzamora, A.B Nieto, Structural relaxation in glasses: numerical exploration of variables of Narayanaswamy and Moynihan's model Journal of Food Engineering. ,vol. 56, pp. 393- 399 ,(2003) , 10.1016/S0260-8774(02)00212-1
Melvin Avrami, Kinetics of Phase Change. I General Theory Journal of Chemical Physics. ,vol. 7, pp. 1103- 1112 ,(1939) , 10.1063/1.1750380