Crystal structures and molecular conformations of mono-6-azido-6-deoxy α-Cyclodextrin and mono-2-O-allyl-α-cyclodextrin -The formation of polymeric helical inclusion complexes

作者: Stephen Hanessian , Aziza Benalil , Michel Simard , Francine Bélanger-Gariépy

DOI: 10.1016/0040-4020(95)00609-C

关键词: ChemistryCyclodextrinHelical polymerInclusion (mineral)CrystallographyMolecular conformationCrystal structure

摘要: Abstract The three dimensional X-ray structures of hydrated mono-6-azido-6-deoxy-α-cyclodextrin 1 and mono-2-O-allyl-α-cyclodextrin 2 were determined. azido allyl groups each cyclodextrin (CD) unit are included in the cavity adjacent units forming a helical polymer.

参考文章(40)
Kazuaki Harata, Kenji Kawano, Kazuhiro Fukunaga, Yoshiro Ohtani, STRUCTURE OF β-CYCLODEXTRIN INCLUSION COMPLEX WITH NICOTINAMIDE Chemical & Pharmaceutical Bulletin. ,vol. 31, pp. 1428- 1430 ,(1983) , 10.1248/CPB.31.1428
Gautam R Desiraju, George W Parshall, Crystal engineering : the design of organic solids Materials Science Monographs. ,vol. 54, ,(1989)
F. J. DiSalvo, Solid-State Chemistry: A A Rediscovered Chemical Frontier Science. ,vol. 247, pp. 649- 655 ,(1990) , 10.1126/SCIENCE.247.4943.649
K. Lindner, W. Saenger, Topography of cyclodextrin inclusion complexes. XVI. Cyclic system of hydrogen bonds: structure of α-cyclodextrin hexahydrate, form (II): comparison with form (I) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 38, pp. 203- 210 ,(1982) , 10.1107/S0567740882002386
Iwao Tabushi, Cyclodextrin catalysis as a model for enzyme action Accounts of Chemical Research. ,vol. 15, pp. 66- 72 ,(1982) , 10.1021/AR00075A001
Christer B. Aakeröy, Kenneth R. Seddon, The hydrogen bond and crystal engineering Chem. Soc. Rev.. ,vol. 22, pp. 397- 407 ,(1993) , 10.1039/CS9932200397
T.D. Inch, G.J. Lewis, R.P. Peel, The influence of steric factors in diazoalkane-pyranosid-2-ulose reactions Carbohydrate Research. ,vol. 19, pp. 29- 38 ,(1971) , 10.1016/S0008-6215(00)80309-2