Equilibrium, thermodynamic and kinetic studies for the biosorption of aqueous lead(II), cadmium(II) and nickel(II) ions on Spirulina platensis

作者: Ayşegül Şeker , Talal Shahwan , Ahmet E. Eroğlu , Sinan Yılmaz , Zeliha Demirel

DOI: 10.1016/J.JHAZMAT.2007.11.007

关键词: Inorganic chemistryNickelCadmiumMetal ions in aqueous solutionBiosorptionChromatographyChemistryFreundlich equationIonic bondingSorptionAqueous solution

摘要: The biosorption of lead(II), cadmium(II) and nickel(II) ions from aqueous solution by Spirulina platensis was studied as a function time, concentration, temperature, repetitive reactivity, ionic competition. kinetic results obeyed well the pseudo second-order model. Freundlich, Dubinin Radushkevich Temkin isotherm models were applied in describing equilibrium partition ions. Freundlich to describe design single-stage batch sorption system. According thermodynamic parameters such ΔG°, ΔH°and ΔS° calculated, process endothermic largely driven towards products. Sorption activities three metal ion system which indicated that there is relative selectivity biosorbent Pb2+ measurements reusability S. large capacity

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