A study on the formation of Ag nanoparticles on the surface and catcher by ion beam irradiation of Ag thin films

作者: Udai B Singh , Dinesh C Agarwal , Saif A Khan , Satyabrata Mohapatra , Ambuj Tripathi

DOI: 10.1088/0022-3727/45/44/445304

关键词: CrystallographySurface plasmon resonanceMaterials scienceAnalytical chemistryNanoparticleIrradiationTransmission electron microscopySputteringThin filmFluenceIonAcoustics and UltrasonicsElectronic, Optical and Magnetic MaterialsSurfaces, Coatings and FilmsCondensed matter physics

摘要: Irradiation of Ag thin films with 100 MeV ions leads to the formation nanoparticles on surface as well catcher, due electronic energy loss mediated sputtering Ag. The experimentally determined sputter yield is found be three orders magnitude higher than values expected for bulk Ag, which explained basis inelastic thermal spike model. confinement in having size smaller electron mean free path (λ) and coverage area results a yield. Transmission microscopy was performed study distribution catcher. variation sputtered particle number constituent atoms follows an inverse power law value exponent (δ) ~ 0.33, at fluence 1 × 1013 cm−2. With increase up 1014 cm−2, additional δ ≈ arises. decreased increased ion-induced sputtering. irradiated sample have partially embedded showing localized plasmon resonance.

参考文章(40)
R. C. Birtcher, S. E. Donnelly, S. Schlutig, Nanoparticle ejection during ion irradiation of gold. Physical Review Letters. ,vol. 85, ,(2000) , 10.1103/PHYSREVLETT.85.4968
A. Wucher, The mass distribution of sputtered metal clusters Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. ,vol. 83, pp. 79- 86 ,(1993) , 10.1016/0168-583X(93)95911-N
Saif A Khan, Devesh K Avasthi, Dinesh C Agarwal, Udai B Singh, Debdulal Kabiraj, None, Quasi-aligned gold nanodots on a nanorippled silica surface: experimental and atomistic simulation investigations. Nanotechnology. ,vol. 22, pp. 235305- ,(2011) , 10.1088/0957-4484/22/23/235305
S.R. Coon, W.F. Calaway, M.J. Pellin, J.M. White, New findings on the sputtering of neutral metal clusters Surface Science. ,vol. 298, pp. 161- 172 ,(1993) , 10.1016/0039-6028(93)90092-X
H. H. Andersen, A. Brunelle, S. Della-Negra, J. Depauw, D. Jacquet, Y. Le Beyec, J. Chaumont, H. Bernas, GIANT METAL SPUTTERING YIELDS INDUCED BY 20-5000 KEV/ATOM GOLD CLUSTERS Physical Review Letters. ,vol. 80, pp. 5433- 5436 ,(1998) , 10.1103/PHYSREVLETT.80.5433
Z G Wang, C Dufour, E Paumier, M Toulemonde, The Se sensitivity of metals under swift-heavy-ion irradiation: a transient thermal process Journal of Physics: Condensed Matter. ,vol. 6, pp. 6733- 6750 ,(1994) , 10.1088/0953-8984/6/34/006
Xiaoyuan Hu, David G. Cahill, Robert S. Averback, Burrowing of Pt nanoparticles into SiO2 during ion-beam irradiation Journal of Applied Physics. ,vol. 92, pp. 3995- 4000 ,(2002) , 10.1063/1.1503387
Z Pászti, G Pető, Z.E Horváth, O Geszti, A Karacs, L Guczi, Formation of supported nanoparticles from island thin films during ion etching Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 178, pp. 131- 134 ,(2001) , 10.1016/S0168-583X(00)00483-3
E. M. Bringa, R. E. Johnson, Coulomb explosion and thermal spikes. Physical Review Letters. ,vol. 88, pp. 165501- ,(2002) , 10.1103/PHYSREVLETT.88.165501
M. Toulemonde, Ch. Dufour, A. Meftah, E. Paumier, Transient thermal processes in heavy ion irradiation of crystalline inorganic insulators Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 166, pp. 903- 912 ,(2000) , 10.1016/S0168-583X(99)00799-5