An Application of Aryl Stationary Phases for Separation of Select Organogermanium Compounds

作者: Mariusz Kluska

DOI: 10.1080/10826070701738845

关键词: SelectivityDichloromethaneSlightly worseSurface modificationStationary phaseGermaniumArylChemistryReversed-phase chromatographyChromatography

摘要: Abstract In this paper are reported the results of continuation investigations concerning optimization chromatographic process benzylgermanium derivatives. Optimal conditions separation and determination have been elaborated for di‐, tri‐, tetra‐benzylhalogeno germanium derivatives using aryl stationary phases. Interaction a π-π type between phase chromatographed compound exhibited predominance in process. During numerous difficulties were observed. These caused, as had shown earlier experiments, by column surface modification. Three phases two mobile taken under consideration. The best selectivity factors α1=3.50 α2=1.46 obtained RP Si‐PGC pure dichloromethane. Slightly worse yielded with naphthyl phase.

参考文章(7)
Mark R Crimmin, Varinder K Aggarwal, Samantha L Riches, Science of Synthesis George Thieme Verlag. ,(2005)
Charles Pidgeon, U.V. Venkataram, Immobilized artificial membrane chromatography: Supports composed of membrane lipids Analytical Biochemistry. ,vol. 176, pp. 36- 47 ,(1989) , 10.1016/0003-2697(89)90269-8
K. Jinno, K. Yamamoto, T. Kuwamoto, H. Nagashima, T. Ueda, S. Tajima, E. Kimura, K. Itoh, J. C. Fetzer, W. R. Biggs, Multidentate phenyl-bonded phases in high-performance liquid chromatography Chromatographia. ,vol. 34, pp. 381- 385 ,(1992) , 10.1007/BF02268372
R. Gadzała-Kopciuch, M. Kluska, M. Wełniak, B. Buszewski, Silicon dioxide surfaces with aryl interaction sites for chromatographic applications Materials Chemistry and Physics. ,vol. 89, pp. 228- 237 ,(2005) , 10.1016/J.MATCHEMPHYS.2004.03.022
Mariusz Kluska, Krzysztof Pypowski, Separation of Tribenzylhydrogermanium Nitrile Derivatives by Means of HPLC with Participation of Π‐Π Interactions Journal of Liquid Chromatography & Related Technologies. ,vol. 30, pp. 2059- 2067 ,(2007) , 10.1080/10826070701435061
Ronald E. Majors, High-performance liquid chromatography on small particle silica gel Analytical Chemistry. ,vol. 44, pp. 1722- 1726 ,(1972) , 10.1021/AC60319A007