Lattice gas model for the metal-electrolyte interface
作者： S.H. Liu
DOI: 10.1016/0039-6028(80)90598-1
关键词: Lattice diffusion coefficient 、 Empty lattice approximation 、 Particle in a one-dimensional lattice 、 Electrolyte 、 Nearly free electron model 、 Condensed matter physics 、 HPP model 、 Lattice energy 、 Electric field 、 Chemistry
摘要: Abstract A lattice model is proposed for the physical properties of metal-electrolyte interface. It shown that near electrode where potential and electric field are very high, continuum Gouy others breaks down, but gives a physically reasonable description electrolyte in interface region.
harvard.edu
elsevier.com
sci-hub.se 参考文章(14)
Mark G. Sceats, M. Stavola, Stuart A. Rice, A zeroth order random network model of liquid water Journal of Chemical Physics. ,vol. 70, pp. 3927- 3938 ,(1979) , 10.1063/1.437945
N.F. Mott, R.J. Watts-Tobin, The interface between a metal and an electrolyte Electrochimica Acta. ,vol. 4, pp. 79- 107 ,(1961) , 10.1016/0013-4686(61)80009-1
Frank H. Stillinger, John G. Kirkwood, Theory of the Diffuse Double Layer The Journal of Chemical Physics. ,vol. 33, pp. 1282- 1290 ,(1960) , 10.1063/1.1731401
David C. Grahame, Effects of Dielectric Saturation upon the Diffuse Double Layer and the Free Energy of Hydration of Ions The Journal of Chemical Physics. ,vol. 18, pp. 903- 909 ,(1950) , 10.1063/1.1747807
R. J. Watts-tobin, The interface between a metal and an electrolytic solution Philosophical Magazine. ,vol. 6, pp. 133- 153 ,(1961) , 10.1080/14786436108238358
J. Ross Macdonald, Carl A. Barlow, Theory of Double‐Layer Differential Capacitance in Electrolytes The Journal of Chemical Physics. ,vol. 36, pp. 3062- 3080 ,(1962) , 10.1063/1.1732426
David C. Grahame, The Electrical Double Layer and the Theory of Electrocapillarity. Chemical Reviews. ,vol. 41, pp. 441- 501 ,(1947) , 10.1021/CR60130A002
F. Booth, The Dielectric Constant of Water and the Saturation Effect The Journal of Chemical Physics. ,vol. 19, pp. 391- 394 ,(1951) , 10.1063/1.1748233
John G. Kirkwood, The Dielectric Polarization of Polar Liquids Journal of Chemical Physics. ,vol. 7, pp. 911- 919 ,(1939) , 10.1063/1.1750343
Derek Y. C. Chan, D. John Mitchell, Barry W. Ninham, A model of solvent structure around ions Journal of Chemical Physics. ,vol. 70, pp. 2946- 2957 ,(1979) , 10.1063/1.437833