Oxidation and combustion of low alkylbenzenes at high pressure: Comparative reactivity and auto-ignition
作者： A. Roubaud , R. Minetti , L.R. Sochet
DOI: 10.1016/S0010-2180(99)00169-8
关键词: Ethylbenzene 、 Ignition system 、 Alkylbenzenes 、 Xylene 、 Analytical chemistry 、 Bar (unit) 、 Propylbenzene 、 Chemistry 、 Organic chemistry 、 Light emission 、 Autoignition temperature
摘要: Abstract The auto-ignition features of 11 alkylbenzenes in a rapid compression machine have been compared for stoichiometric mixtures the lower temperature region (600–900 K), and at compressed pressures up to 25 bar, by following pressure traces light emission. They are classified two groups. Toluene, m -xylene, p 1,3,5-trimethylbenzene ignite only above 900 K 16 bar. o -Xylene, ethylbenzene, 1,2,3-trimethylbenzene, 1,2,4-trimethylbenzene, n -propylbenzene, 2-ethyltoluene, -butylbenzene much pressure. second group shows complex phenomenology similar alkanes alkenes when submitted adapted conditions reactant concentrations. Ignition steps negative dependence ignition delays observed favorable cases. Some them show low-temperature luminescence. -xylene similar, spite their dissimilar molecular structure. higher degree reactivity is ascribed close proximity and/or length alkyl chains.
elsevier.com
sci-hub.se 参考文章(9)
J.A. Barnard, B.M. Sankey, The slow combustion of the isomeric xylenes I—Meta- and para-xylene Combustion and Flame. ,vol. 12, pp. 345- 352 ,(1968) , 10.1016/0010-2180(68)90039-4
The combustion of aromatic and alicyclic hydrocarbons. III. Ignition and cool-flame characteristics Proc. R. Soc. Lond. A. ,vol. 174, pp. 379- 393 ,(1940) , 10.1098/RSPA.1940.0027
K.C. Salooja, Studies of combustion processes leading to ignition of aromatic hydrocarbons Combustion and Flame. ,vol. 9, pp. 121- 129 ,(1965) , 10.1016/0010-2180(65)90058-1
J.A. Barnard, B.M. Sankey, The slow combustion of the isomeric xylenes II—Ortho-xylene Combustion and Flame. ,vol. 12, pp. 353- 359 ,(1968) , 10.1016/0010-2180(68)90040-0
J.F. Griffiths, P.A. Halford-Maw, C. Mohamed, Spontaneous ignition delays as a diagnostic of the propensity of alkanes to cause engine knock Combustion and Flame. ,vol. 111, pp. 327- 337 ,(1997) , 10.1016/S0010-2180(97)00004-7
The Combustion of Aromatic and Alicyclic Hydrocarbons. IV. The Kinetics of the Slow Combustion of Benzene and Its Mono-Alkyl Derivatives at Low Temperatures Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 174, pp. 394- 409 ,(1940) , 10.1098/RSPA.1940.0028
The Combustion of Aromatic and Alicyclic Hydrocarbons. I. The Slow Combustion of Benzene, Toluene, Ethylbenzene, n-Propylbenzene, n-Butylbenzene, o-Xylene, m-Xylene, p-Xylene and Mesitylene Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 161, pp. 48- 67 ,(1937) , 10.1098/RSPA.1937.0131
R. MINETTI, M. RIBAUCOUR, M. CARLIER, L R. SOCHET, Autoignition Delays of a Series of Linear and Branched Chain Alkanes in the Intermediate Range of Temperature Combustion Science and Technology. ,vol. 113, pp. 179- 192 ,(1996) , 10.1080/00102209608935493
M Ribaucour, R Minetti, M Carlier, LR Sochet, Autoinflammation à haute pression. Conception, réalisation et test d'une machine à compression rapide Journal de Chimie Physique. ,vol. 89, pp. 2127- 2152 ,(1992) , 10.1051/JCP/1992892127