Conductivity tuning of the ITO sol-gel materials by adjusting the tin oxide concentration, morphology and the crystalline size

作者: Roya Baghi , Kun Zhang , Shiren Wang , Louisa J. Hope-Weeks

DOI: 10.1016/J.MICROMESO.2016.10.045

关键词: CrystalliteConductivityDopantIndium tin oxideMesoporous materialTin oxideMaterials scienceChemical engineeringParticle sizeMicrostructureNanotechnology

摘要: Abstract A facile epoxide-driven method has been used to synthesize a series of highly electrically conductive mesoporous indium tin oxide (ITO) sol-gel nanomaterials with different morphologies and particle sizes. By altering the Sn content, morphology size these materials undergo drastic change. The effect ultimately results in significant changes observed conductance materials. It became apparent that increasing dopant concentration In2O3 matrix resulted an increase average crystallite present material. Additionally, modifies which at low exhibit sponge-like microstructure gradually spherical-type architecture as increases. coupling changing observable difference conductivity. There was general conductivity correlated maximum being for sample 17 wt% Sn. Increasing above this point decrease This work provides simple tune ITO aerogels by simply modify within

参考文章(31)
Shi-min Liu, Wan-yu Ding, Wei-ping Chai, Preparation and characterization of highly dispersed and crystallised ITO nanoparticles Materials Letters. ,vol. 65, pp. 1272- 1275 ,(2011) , 10.1016/J.MATLET.2011.01.047
Xiaohong Sun, Yifeng Shi, Huiming Ji, Xiaolei Li, Shu Cai, Chunming Zheng, Nanocasting synthesis of ordered mesoporous indium tin oxide (ITO) materials with controllable particle size and high thermal stability Journal of Alloys and Compounds. ,vol. 545, pp. 5- 11 ,(2012) , 10.1016/J.JALLCOM.2012.08.003
László Kőrösi, Alice Scarpellini, Péter Petrik, Szilvia Papp, Imre Dékány, Sol–gel synthesis of nanostructured indium tin oxide with controlled morphology and porosity Applied Surface Science. ,vol. 320, pp. 725- 731 ,(2014) , 10.1016/J.APSUSC.2014.09.178
Marauo Davis, Kun Zhang, Shiren Wang, Louisa J. Hope-Weeks, Enhanced electrical conductivity in mesoporous 3D indium-tin oxide materials Journal of Materials Chemistry. ,vol. 22, pp. 20163- 20165 ,(2012) , 10.1039/C2JM34744J
Roya Baghi, Geneva R. Peterson, Louisa J. Hope-Weeks, Thermal tuning of advanced Cu sol–gels for mixed oxidation state Cu/CuxOy materials Journal of Materials Chemistry. ,vol. 1, pp. 10898- 10902 ,(2013) , 10.1039/C3TA11957B
Oliver Bierwagen, Indium oxide—a transparent, wide-band gap semiconductor for (opto)electronic applications Semiconductor Science and Technology. ,vol. 30, pp. 024001- ,(2015) , 10.1088/0268-1242/30/2/024001
Bong-Chull Kim, Joon-Hyung Lee, Jeong-Joo Kim, Takayasu Ikegami, None, Rapid rate sintering of nanocrystalline indium tin oxide ceramics: particle size effect Materials Letters. ,vol. 52, pp. 114- 119 ,(2002) , 10.1016/S0167-577X(01)00377-9
Ning Wang, Xiaoxin Liu, Xingyuan Liu, None, Ultraviolet luminescent, high-effective-work-function LaTiO3-doped indium oxide and its effects in organic optoelectronics. Advanced Materials. ,vol. 22, pp. 2211- 2215 ,(2010) , 10.1002/ADMA.200903987
Alexander E. Gash, Thomas M. Tillotson, Joe H. Satcher, John F. Poco, Lawrence W. Hrubesh, Randall L. Simpson, Use of Epoxides in the Sol−Gel Synthesis of Porous Iron(III) Oxide Monoliths from Fe(III) Salts Chemistry of Materials. ,vol. 13, pp. 999- 1007 ,(2001) , 10.1021/CM0007611
Preston Brown, Deóis Ua Cearnaigh, Emily K. Fung, Louisa J. Hope-Weeks, Controlling the morphology of a zinc ferrite-based aerogel by choice of solvent Journal of Sol-Gel Science and Technology. ,vol. 61, pp. 104- 111 ,(2012) , 10.1007/S10971-011-2597-2