Development of Electro-Spun Poly (Vinyl Alcohol)/Titanium Dioxide Membrane-Based Polymer Electrolytes for Lithium-Ion Batteries
作者： Mahvash Shokrollahi , Mohammad Morshed , Dariush Semnani , Behzad Rezaei , None
DOI: 10.1080/00914037.2013.812087
关键词: Materials science 、 Lithium 、 Nanofiber 、 Membrane 、 Lithium perchlorate 、 Vinyl alcohol 、 Chemical engineering 、 Electrospinning 、 Cyclic voltammetry 、 Electrolyte 、 Inorganic chemistry
摘要: Composite nanofiber membranes were prepared by electrospinning from poly (vinyl alcohol)/titanium dioxide blend solutions with different amounts of TiO2 nanoparticles. These exhibited a high porosity 79–91%. The results thermogravimetric analysis revealed improved thermal stability in due to presence TiO2. Polymer electrolytes are activating the lithium perchlorate liquid electrolyte. electrolyte uptake, which reached 659%. Moreover, incorporation into ionic conductivity. Cyclic voltammetry measurement lithium/polymer 20 wt% TiO2/lithium cell was performed at scan rate 0.1 Vs−1 between −1.00 and +1.00 V. that Li/polymer electrochemical behavior markedly stabilized after initial cycles. This indicated that, following an stabilization period, polymer capable supporting f...
sci-hub.se 参考文章(40)
Fengmei Shi, Yuxin Ma, Jun Ma, Panpan Wang, Weixiao Sun, Preparation and characterization of PVDF/TiO2 hybrid membranes with different dosage of nano-TiO2 Journal of Membrane Science. ,vol. 389, pp. 522- 531 ,(2012) , 10.1016/J.MEMSCI.2011.11.022
A SUBRAMANIA, N KALYANASUNDARAM, N SUKUMAR, Development of PVA based micro-porous polymer electrolyte by a novel preferential polymer dissolution process Journal of Power Sources. ,vol. 141, pp. 188- 192 ,(2005) , 10.1016/J.JPOWSOUR.2004.09.001
Young-Jin Kim, Chang Hyun Ahn, Myung Bok Lee, Myung-Seok Choi, Characteristics of electrospun PVDF/SiO2 composite nanofiber membranes as polymer electrolyte Materials Chemistry and Physics. ,vol. 127, pp. 137- 142 ,(2011) , 10.1016/J.MATCHEMPHYS.2011.01.046
Muhammad Ali Zulfikar, A Wahab Mohammad, Abdul Amir Kadhum, Nidal Hilal, None, Poly(methyl methacrylate)/SIO2 hybrid membranes: Effect of solvents on structural and thermal properties Journal of Applied Polymer Science. ,vol. 99, pp. 3163- 3171 ,(2006) , 10.1002/APP.22862
Tae-Hyung Cho, Masanao Tanaka, Hiroshi Onishi, Yuka Kondo, Tatsuo Nakamura, Hiroaki Yamazaki, Shigeo Tanase, Tetsuo Sakai, Battery performances and thermal stability of polyacrylonitrile nano-fiber-based nonwoven separators for Li-ion battery Journal of Power Sources. ,vol. 181, pp. 155- 160 ,(2008) , 10.1016/J.JPOWSOUR.2008.03.010
Anantha Iyengar Gopalan, Kwang-Pill Lee, Kalayil Manian Manesh, Padmanabhan Santhosh, Poly(vinylidene fluoride)–polydiphenylamine composite electrospun membrane as high-performance polymer electrolyte for lithium batteries Journal of Membrane Science. ,vol. 318, pp. 422- 428 ,(2008) , 10.1016/J.MEMSCI.2008.03.007
M SAIRAM, M PATIL, R VEERAPUR, S PATIL, T AMINABHAVI, Novel dense poly(vinyl alcohol)–TiO2 mixed matrix membranes for pervaporation separation of water–isopropanol mixtures at 30 °C ☆ Journal of Membrane Science. ,vol. 281, pp. 95- 102 ,(2006) , 10.1016/J.MEMSCI.2006.03.022
S Rajendran, M Sivakumar, R Subadevi, Investigations on the effect of various plasticizers in PVA–PMMA solid polymer blend electrolytes Materials Letters. ,vol. 58, pp. 641- 649 ,(2004) , 10.1016/S0167-577X(03)00585-8
Bruno Scrosati, Fausto Croce, Stefania Panero, Progress in lithium polymer battery R&D Journal of Power Sources. ,vol. 100, pp. 93- 100 ,(2001) , 10.1016/S0378-7753(01)00886-2
Zhang Liuxue, Wang Xiulian, Liu Peng, Su Zhixing, Low temperature deposition of TiO2 thin films on polyvinyl alcohol fibers with photocatalytical and antibacterial activities Applied Surface Science. ,vol. 254, pp. 1771- 1774 ,(2008) , 10.1016/J.APSUSC.2007.07.145