Sulfonation and Trifluoromethylation of Enol Acetates with Sulfonyl Chlorides Using Visible-Light Photoredox Catalysis

作者: Heng Jiang , Yuanzheng Cheng , Yan Zhang , Shouyun Yu

DOI: 10.1002/EJOC.201300693

关键词: Visible spectrumPhotoredox catalysisTrifluoromethylationPhotochemistrySulfonylEnolChemistry

摘要: A mild, practical method to prepare α-sulfonyl and α-trifluoromethyl ketones from readily available enol acetates sulfonyl chlorides has been developed using visible-light photoredox catalysis. The could be used with a wide range of chlorides, gave the desired products in satisfactory excellent yields.

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