Enzymatic resolution of 1,1-dimethoxybut-3-en-2-ol and 1,1-dimethoxypent-4-en-2-ol, α-hydroxyaldehyde precursors for aldol-type reactions
作者： Robert Chênevert , Sébastien Gravil , Jean Bolte
DOI: 10.1016/J.TETASY.2005.05.013
关键词: Vinyl acetate 、 Stereoselectivity 、 Enantiomer 、 Reversible reaction 、 Acylation 、 Aldol reaction 、 Enzymatic hydrolysis 、 Enzyme 、 Organic chemistry 、 Chemistry
摘要: Hydroxyacetals 2 and 3 were resolved by acylation with vinyl acetate in the presence of lipases organic media. The reverse reaction, enzymatic hydrolysis corresponding acetates, was also highly stereoselective provided opposite enantiomers.
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