Internal‐Friction Study of High‐Purity Single Crystals ofnEicosane (C20H42)

作者: J. M. Crissman , E. Passaglia

DOI: 10.1063/1.1659833

关键词: MaximaCrystallographyDislocationIrradiationCrystallographic defectCrystalliteMaterials scienceImpuritySingle crystalWork (thermodynamics)General Physics and Astronomy

摘要: Large pure single crystals of n eicosane (C20H42) with [210] growth axes have been prepared by slow crystallizations from the melt. Internal‐friction measurements covering temperatures 100 to 300 K at ≃ 1 kHz reveal that in as‐grown both α and γ loss peaks characteristic polycrystalline alkanes less purity are absent, which we conclude that, polycrystals, these processes a result impurities and/or crystal defects. Two very weak maxima obscure origin were observed about 270 287 for all studies. In one progressive stages light cold work induced complex spectrum small between 200 K. These found be highly sensitive aging. We believe behavior provides evidence dislocation motion this type. No detectable peak resulted work. Data also included was irradiated rays.

参考文章(16)
K. L. DeVries, B. A. Lloyd, M. L. Williams, Reaction‐Rate Model for Fracture in Polymeric Fibers Journal of Applied Physics. ,vol. 42, pp. 4644- 4653 ,(1971) , 10.1063/1.1659834
J. M. Crissman, E. Passaglia, R. K. Eby, J. P. Colson, Crystal data on n‐eicosane (C20H42) Journal of Applied Crystallography. ,vol. 3, pp. 194- 195 ,(1970) , 10.1107/S0021889870005988
H. K. Welsh, The modification of dielectric absorption in molecular crystals by impurities and plastic deformation Transactions of the Faraday Society. ,vol. 55, pp. 52- 60 ,(1959) , 10.1039/TF9595500052
J. S. Dryden, H. K. Welsh, Dielectric absorption and imperfections in long-chain esters Transactions of the Faraday Society. ,vol. 60, pp. 2135- 2143 ,(1964) , 10.1039/TF9646002135
K. M. Sinnott, Mechanical Relaxations in Single Crystals of Polyethylene Journal of Applied Physics. ,vol. 37, pp. 3385- 3400 ,(1966) , 10.1063/1.1708869
Kenji Tsuge, Hideo Enjoji, Hiroshi Terada, Yoshiyuki Ozawa, Yasuku Wada, Mechanical Dispersion and Molecular Motion in Crystals of Polyethylene and Other Polymers Japanese Journal of Applied Physics. ,vol. 1, pp. 270- 276 ,(1962) , 10.1143/JJAP.1.270
D. Bloor, G. D. Dean, Growth and morphology of large single crystals of long chainn-paraffins and ketones Journal of Materials Science. ,vol. 5, pp. 752- 761 ,(1970) , 10.1007/BF00562161
R. J. Meakins, The magnitude of the dielectric absorption in solid aliphatic long-chain compounds Transactions of the Faraday Society. ,vol. 55, pp. 1701- 1704 ,(1959) , 10.1039/TF9595501701
Toshiaki Hayashida, Crystal Structure of Triclinic Form of n-Octadecane Journal of the Physical Society of Japan. ,vol. 17, pp. 306- 315 ,(1962) , 10.1143/JPSJ.17.306
Joan W. Arnold, R. J. Meakins, Effect of cold working on dielectric properties of crystalline long-chain compounds Transactions of the Faraday Society. ,vol. 51, pp. 1667- 1673 ,(1955) , 10.1039/TF9555101667