Effects of Al3Ta/TaN Bilayered Diffusion Barriers in the Al/Si Contact Systems

作者: Mayumi Takeyama , Atsushi Noya , Katsutaka Sasaki

DOI: 10.1143/JJAP.35.699

关键词: Structural changeComposite materialDiffractionMineralogyThermal stabilityMinimum free energyChemistryGrain growthAnnealing (metallurgy)Contact systemThin film

摘要: A thermally stable contact system of Al/Al3Ta/TaN/Si, which tolerates post-metallization annealing even at 600° C for 1 h, was successfully prepared by achieving a state chemical pseudo-equilibrium the interface Al/Al3Ta and that Al3Ta/TaN. No solid-phase reactions took place these interfaces due to realization minimum free energy states. The thermal stability in discussed from point view reaction thin films. It also revealed X-ray diffraction analysis absence structural change grain growth both TaN Al3Ta layers is effective total system. We have been able demonstrate validity realizing preparing systems.

参考文章(4)
Thaddeus B Massalski, Hiroaki Okamoto, PRnbsp Subramanian, Linda Kacprzak, William W Scott, None, Binary alloy phase diagrams ASM International. ,vol. 3, pp. 2874- ,(1986)
Atsushi Noya, Mayumi Takeyama, Katsutaka Sasaki, Eiji Aoyagi, Kenji Hiraga, Thermal Stability ofW2NFilm as a Diffusion Barrier between Al and Si Japanese Journal of Applied Physics. ,vol. 33, pp. 1528- 1529 ,(1994) , 10.1143/JJAP.33.1528
Atsushi Noya, Katsutaka Sasaki, Mayumi Takeyama, Auger Electron Spectroscopy Study on the Stability and the Interfacial Reaction of Ta, Ta-N and TaN Films as a Diffusion Barrier between Cu9Al4Film and Si Japanese Journal of Applied Physics. ,vol. 32, pp. 911- 915 ,(1993) , 10.1143/JJAP.32.911
A. O. Ibidunni, R. L. Masaitis, R. L. Opila, A. J. Davenport, H. S. Isaacs, J. A. Taylor, Characterization of the oxidation of tantalum nitride Surface and Interface Analysis. ,vol. 20, pp. 559- 564 ,(1993) , 10.1002/SIA.740200703