Surface modification of InP by plasma techniques using hydrogen and oxygen

作者: D.T. Clark , T. Fok

DOI: 10.1016/0040-6090(89)90593-2

关键词: PhosphineOverlayerPlasmaHydrogenElectron spectroscopyInorganic chemistrySurface modificationMaterials sciencePhosphideOxygen

摘要: Abstract The surface chemistry of InP substrates for use in the fabrication electronic devices (MIS structures) was specifically modified by means inductively coupled plasmas excited oxygen and hydrogen results such treatments were elaborated electron spectroscopy chemical analysis. Oxygen plasma give a controlled oxidized overlayer which reaches limiting thickness as function treatment time. InPO 4 thus produced is considerably thicker than natural extended atmospheric exposure. For uncontaminated surfaces, produces indium metal an overlayer, phosphide being reduced to phosphine. Exposure samples leads composite structure consisting In 2 O 3 on ImP. with patched overlayers , reduction but not phosphate.

参考文章(6)
J. C. Knights, R. A. Lujan, Microstructure of plasma‐deposited a‐Si : H films Applied Physics Letters. ,vol. 35, pp. 244- 246 ,(1979) , 10.1063/1.91086
G.G. Roberts, K.P. Pande, W.A. Barlow, Inp/langmuir-film m.i.s.f.e.t. Iee Journal on Solidstate and Electron Devices. ,vol. 2, pp. 169- 175 ,(1978) , 10.1049/IJ-SSED.1978.0053
D. T. Clark, A. Dilks, Esca applied to polymers. XXIII. RF glow discharge modification of polymers in pure oxygen and helium–oxygen mixtures Journal of Polymer Science: Polymer Chemistry Edition. ,vol. 17, pp. 957- 976 ,(1979) , 10.1002/POL.1979.170170404