Ag-catalyzed C–H/C–C bond functionalization

作者: Qing-Zhong Zheng , Ning Jiao

DOI: 10.1039/C6CS00107F

关键词: Combinatorial chemistryOrganic chemistryTransition metalSurface modificationLewis acids and basesMetalCatalytic efficiencyChemistryCatalysis

摘要: Silver, known and utilized since ancient times, is a coinage metal, which has been widely used for various organic transformations in the past few decades. Currently, silver-catalyzed reaction one of frontier areas chemistry, progress research this field very rapid. Compared with other transition metals, silver long believed to have low catalytic efficiency, most commonly, it as either cocatalyst or Lewis acid. Interestingly, discovery Ag-catalysis significantly improved recent years. Especially, Ag(I) demonstrated an important versatile catalyst variety transformations. However, so far, there no systematic review on Ag-catalyzed C–H/C–C bond functionalization. In review, we will focus development functionalization corresponding mechanism.

参考文章(209)
Shuai Mao, Xue-Qing Zhu, Ya-Ru Gao, Dong-Dong Guo, Yong-Qiang Wang, Silver‐Catalyzed Coupling of Two C sp 3H Groups and One‐Pot Synthesis of Tetrasubstituted Furans, Thiophenes, and Pyrroles Chemistry: A European Journal. ,vol. 21, pp. 11335- 11339 ,(2015) , 10.1002/CHEM.201501410
William S. Emerson, The Preparation of Amines by Reductive Alkylation Organic Reactions. pp. 174- 255 ,(2011) , 10.1002/0471264180.OR004.03
Qingwen Gui, Liang Hu, Xiang Chen, Jidan Liu, Ze Tan, Stereoselective synthesis of vinylphosphonates and phosphine oxides via silver-catalyzed phosphorylation of styrenes Chemical Communications. ,vol. 51, pp. 13922- 13924 ,(2015) , 10.1039/C5CC04826E
Gaobo Hu, Yun Zhang, Jue Su, Zezhou Li, Yuxing Gao, Yufen Zhao, Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides Organic and Biomolecular Chemistry. ,vol. 13, pp. 8221- 8231 ,(2015) , 10.1039/C5OB00959F
So Won Youn, Tae Yun Ko, Min Jung Jang, Su San Jang, Silver(I)-Mediated CH Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude Advanced Synthesis & Catalysis. ,vol. 357, pp. 227- 234 ,(2015) , 10.1002/ADSC.201400759
Jiajia Yu, Huijun Zhao, Shuguang Liang, Xiaoguang Bao, Chen Zhu, A facile and regioselective synthesis of 1-tetralones via silver-catalyzed ring expansion Organic and Biomolecular Chemistry. ,vol. 13, pp. 7924- 7927 ,(2015) , 10.1039/C5OB01222H
Supasorn Phae-nok, Darunee Soorukram, Chutima Kuhakarn, Vichai Reutrakul, Manat Pohmakotr, Silver-Mediated Decarboxylative Fluorination of Paraconic Acids: A Direct Entry to β-Fluorinated γ-Butyrolactones European Journal of Organic Chemistry. ,vol. 2015, pp. 2879- 2888 ,(2015) , 10.1002/EJOC.201500023
Guichun Fang, Xihe Bi, Silver-catalysed reactions of alkynes: recent advances Chemical Society Reviews. ,vol. 44, pp. 8124- 8173 ,(2015) , 10.1039/C5CS00027K
Zhengkai Chen, Binjie Wang, Jitan Zhang, Wenlong Yu, Zhanxiang Liu, Yuhong Zhang, Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups Organic chemistry frontiers. ,vol. 2, pp. 1107- 1295 ,(2015) , 10.1039/C5QO00004A