作者: Qing-Zhong Zheng , Ning Jiao
DOI: 10.1039/C6CS00107F
关键词: Combinatorial chemistry 、 Organic chemistry 、 Transition metal 、 Surface modification 、 Lewis acids and bases 、 Metal 、 Catalytic efficiency 、 Chemistry 、 Catalysis
摘要: Silver, known and utilized since ancient times, is a coinage metal, which has been widely used for various organic transformations in the past few decades. Currently, silver-catalyzed reaction one of frontier areas chemistry, progress research this field very rapid. Compared with other transition metals, silver long believed to have low catalytic efficiency, most commonly, it as either cocatalyst or Lewis acid. Interestingly, discovery Ag-catalysis significantly improved recent years. Especially, Ag(I) demonstrated an important versatile catalyst variety transformations. However, so far, there no systematic review on Ag-catalyzed C–H/C–C bond functionalization. In review, we will focus development functionalization corresponding mechanism.