Modern liquid chromatographic techniques for the separation of Nd and Sr for isotopic analyses
作者： R.M. Cassidy , C. Chauvel
DOI: 10.1016/0009-2541(89)90031-4
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摘要: Cassidy, R.M. and Chauvel, C., 1989. Modern liquid chromatographic techniques for the separation of Nd Sr fl)r isotopic analyses. Chem. Geol., 74: 189-200. A conventional high-performance chromatograph (HPLC) has been evaluated rapid isolation pure fractions Nd, Sr, Sm Rb from dissolved-rock solutions. Fractions Rb, +Sm were separated in 10 rain. a rock solution, one another with second 10-rain. separation. cleaner than those obtained by classical ion-exchange procedures, stable-ion signals containing >~ 30 ng Nd. Conventional laboratory facilities used all HPLC procedures except filament loading, total sample blanks 80 pg 250 Sr. No significant mass interferences observed or fractions. The agreement between results ~VSr/S~Sr ~4:~Nd/144Nd ratios was within +_ 0.003% ( l a) BCR-1 standard number basalts phonolites.
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sci-hub.se 参考文章(10)
R. M. Cassidy, S. Elchuck, K. S. Joel, Experimental Considerations in the Practice of Metal Ion Separations by Dynamic Exchange Techniques Springer, Dordrecht. pp. 40- 48 ,(1987) , 10.1007/978-94-009-3449-8_5
Catherine Chauvel, Bernard Dupré, George A. Jenner, The Sm-Nd age of Kambalda volcanics is 500 Ma too old! Earth and Planetary Science Letters. ,vol. 74, pp. 315- 324 ,(1985) , 10.1016/S0012-821X(85)80003-0
R. M. Cassidy, F. C. Miller, C. H. Knight, J. C. Roddick, R. W. Sullivan, Evaluation of dynamic ion exchanger for the isolation of metal ions for characterization by mass and .alpha.-spectrometry Analytical Chemistry. ,vol. 58, pp. 1389- 1394 ,(1986) , 10.1021/AC00298A027
R. M. Cassidy, S. Elchuk, Purnendu K. Dasgupta, Performance of annular membrane and screen-tee reactors for postcolumn-reaction detection of metal ions separated by liquid chromatography Analytical Chemistry. ,vol. 59, pp. 85- 90 ,(1987) , 10.1021/AC00128A018
William M. White, Jonathan Patchett, HfNdSr isotopes and incompatible element abundances in island arcs: implications for magma origins and crust-mantle evolution Earth and Planetary Science Letters. ,vol. 67, pp. 167- 185 ,(1984) , 10.1016/0012-821X(84)90112-2
R. M. Cassidy, S. Elchuk, N. L. Elliot, L. W. Green, C. H. Knight, B. M. Recoskie, Dynamic ion exchange chromatography for the determination of number of fissions in uranium dioxide fuels Analytical Chemistry. ,vol. 58, pp. 1181- 1186 ,(1986) , 10.1021/AC00297A045
D. J. Barkley, Marcia. Blanchette, R. M. Cassidy, Steve. Elchuk, Dynamic chromatographic systems for the determination of rare earths and thorium in samples from uranium ore refining processes Analytical Chemistry. ,vol. 58, pp. 2222- 2226 ,(1986) , 10.1021/AC00124A023
G.R. Choppin, R.J. Silva, SEPARATION OF THE LANTHANIDES BY ION EXCHANGE WITH ALPHA-HYDROXY ISOBUTYRIC ACID Journal of Inorganic and Nuclear Chemistry. ,vol. 3, pp. 153- 154 ,(1956) , 10.1016/0022-1902(56)80076-6
R.M. Cassidy, Determination of rare-earth elements in rocks by liquid chromatography Chemical Geology. ,vol. 67, pp. 185- 195 ,(1988) , 10.1016/0009-2541(88)90127-1
R. M. Cassidy, S. Elchuk, Dynamic and Fixed-Site Ion-Exchange Columns with Conductometric Detection for the Separation of Inorganic Anions Journal of Chromatographic Science. ,vol. 21, pp. 454- 459 ,(1983) , 10.1093/CHROMSCI/21.10.454