Grafting of chitosan-acrylamide hybrid on the wool: Characterization, reactive dyeing, antioxidant and antibacterial studies

作者: Mousa Sadeghi-Kiakhani , Siyamak Safapour , Fatemeh Ghanbari-Adivi

DOI: 10.1016/J.IJBIOMAC.2019.05.144

关键词:

摘要: Abstract This study presents a new approach to enhance reactive dye uptake and functional finishing of wool yarns via simple grafting with synthesized chitosan-acrylamide (Ch-Ac) hybrid. To this, Ch-Ac was characterized fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) X-ray diffraction (XRD) techniques. Then, grafted on wool, FTIR, SEM, weight gain analysis dyeability two commercial dyes. Results showed that treated could be dyed at lower temperatures (ca. 40 °C), times 30 min), amount (2% owf) as compared raw wool. Also, deeper shades not obtainable in conventional dyeing attained using In addition, treatment imparted very good radical scavenging excellent antibacterial activity against gram-negative (E. coli) gram-positive (S. aureus) bacteria. Color fastness results confirmed had no adverse effect durability dyes washing, light, rubbing perspiration. The this clearly indicated can used eco-friendly enhanced uptake, minimized residual wastewater, saving consumption chemicals, energy, time dyeing.

参考文章(38)
Daniela Enescu, Use of chitosan in surface modification of textile materials Bucharest University, Roumanian Society of Biological Sciences. ,vol. 13, pp. 4037- 4048 ,(2008)
Mousa Sadeghi-Kiakhani, Siyamak Safapour, Salt-free reactive dyeing of the cotton fabric modified with chitosan-poly(propylene imine) dendrimer hybrid Fibers and Polymers. ,vol. 16, pp. 1075- 1081 ,(2015) , 10.1007/S12221-015-1075-9
Mousa Sadeghi-Kiakhani, Siyamak Safapour, Improvement of dyeing and antimicrobial properties of nylon fabrics modified using chitosan-poly(propylene imine) dendreimer hybrid Journal of Industrial and Engineering Chemistry. ,vol. 33, pp. 170- 177 ,(2016) , 10.1016/J.JIEC.2015.09.034
Norio Tsubokawa, Takeshi Takayama, Surface modification of chitosan powder by grafting of ‘dendrimer-like’ hyperbranched polymer onto the surface Reactive and Functional Polymers. ,vol. 43, pp. 341- 350 ,(2000) , 10.1016/S1381-5148(99)00065-6
Luminita Balau, Gabriela Lisa, M. Popa, V. Tura, V. Melnig, Physico-chemical properties of Chitosan films Central European Journal of Chemistry. ,vol. 2, pp. 638- 647 ,(2004) , 10.2478/BF02482727
Claudia Vineis, Fabio Rombaldoni, Monica Periolatto, Franco Ferrero, Multifunctional finishing of wool fabrics by chitosan UV-grafting: An approach Carbohydrate Polymers. ,vol. 98, pp. 624- 629 ,(2013) , 10.1016/J.CARBPOL.2013.06.054
Sudheesh K Shukla, Ajay K Mishra, Omotayo A Arotiba, Bhekie B Mamba, None, Chitosan-based nanomaterials: A state-of-the-art review International Journal of Biological Macromolecules. ,vol. 59, pp. 46- 58 ,(2013) , 10.1016/J.IJBIOMAC.2013.04.043
Hitoshi Sashiwa, Yoshihiro Shigemasa, Rene Roy, Chemical modification of chitosan 11: chitosan–dendrimer hybrid as a tree like molecule Carbohydrate Polymers. ,vol. 49, pp. 195- 205 ,(2002) , 10.1016/S0144-8617(01)00322-8
V.K. Mourya, Nazma N. Inamdar, Chitosan-modifications and applications: Opportunities galore Reactive & Functional Polymers. ,vol. 68, pp. 1013- 1051 ,(2008) , 10.1016/J.REACTFUNCTPOLYM.2008.03.002
SM Gawish, MA Saudy, SM Abo El‐Ola, A Abou‐El‐Kheir, None, The effect of low‐temperature plasma for improving wool and chitosan‐treated wool fabric properties Journal of The Textile Institute. ,vol. 102, pp. 180- 188 ,(2011) , 10.1080/00405000.2010.483836