Herbicide analysis by micellar electrokinetic capillary chromatography

作者: Kumar V. Penmetsa , Ross B. Leidy , Damian Shea

DOI: 10.1016/0021-9673(96)00185-9

关键词:

摘要: Capillary electrophoresis with ultraviolet detection (CE-UV) and laser-induced fluorescence (CE-LIF) was used for analysis of a group herbicides that have widespread use in the USA. CE-UV employed simultaneous determination atrazine, simazine, alachlor metolachlor water. In addition, also suitable dicamba, 2,4-D chlorimuron ethyl. Dicamba, ethyl were analyzed using CE-LIF following derivatization fluorescent reagents. Dicamba derivatized 4-bromomethyl-7-methoxycoumarin dansyl chloride hydrolysis. The limit simazine 0.1 μg/l 1.0 μg/l. estimated 10 ng/l. Our results demonstrate CE provides powerful new analytical tool herbicide analysis.

参考文章(22)
James P. Landers, Handbook of Capillary Electrophoresis ,(1993)
D. D. Kaufman, P. C. Kearney, Herbicides: Chemistry, Degradation, and Mode of Action ,(1976)
M. Sharma, R. Jain, E. Ionescu, H.K. Slocum, Capillary Electrophoretic Separation and Laser-Induced Fluorescence Detection of the Major DNA Adducts of Cisplatin and Carboplatin Analytical Biochemistry. ,vol. 228, pp. 307- 311 ,(1995) , 10.1006/ABIO.1995.1355
Yuk Y. Wigfield, Kathleen A. McCormack, Ralph. Grant, Simultaneous determination of residues of paraquat and diquat in potatoes using high-performance capillary electrophoresis with a ultraviolet detection Journal of Agricultural and Food Chemistry. ,vol. 41, pp. 2315- 2318 ,(1993) , 10.1021/JF00036A018
Wilfred E. Pereira, Frances D. Hostettler, Nonpoint source contamination of the Mississippi River and its tributaries by herbicides Environmental Science & Technology. ,vol. 27, pp. 1542- 1552 ,(1993) , 10.1021/ES00045A008
Gaël Durand, Véronique Bouvot, Damià Barceló, Determination of trace levels of herbicides in estuarine waters by gas and liquid chromatographic techniques Journal of Chromatography A. ,vol. 607, pp. 319- 327 ,(1992) , 10.1016/0021-9673(92)87091-L
Kumar V. Penmetsa, Damian Shea, Ross B. Leidy, James A. Bond, Analysis of benzo[a]pyrene‐DNA adducts by capillary electrophoresis with laser‐induced fluroescence detection Hrc-journal of High Resolution Chromatography. ,vol. 18, pp. 719- 720 ,(1995) , 10.1002/JHRC.1240181110