Simple fabrication of active electrodes using direct laser transference

作者: P. Cavallo , R. Coneo Rodriguez , M. Broglia , D.F. Acevedo , C.A. Barbero

DOI: 10.1016/J.ELECTACTA.2013.10.146

关键词:

摘要: Direct laser transference (DLT) method is applied to obtain electrodes modified with thin films of conducting polymers (CPs) or catalytic metals. A short (6–10 ns) pulse light (second harmonic Nd-YAG Laser, λ = 532 nm) shined on the backside a (<200 nm) film material be transferred, which deposited transparent substrate. The illuminated region heats up and (conducting polymer metal) thermally transferred solid target placed at distance in air. In that ways, CPs are onto polypropylene, glass, indium doped tin oxide (ITO), glassy carbon gold films. same manner, electrocatalytic metals (platinum gold) conductive substrates (glassy ITO glass). have been characterized by scanning electron microscopy, cyclic voltammetry, atomic force UV-visible Fourier Transform Infrared spectroscopies. chemical, electrical redox properties polymeric materials remain unaltered after transfer. Moreover, CP multilayers can built applying DLT several times Besides polyaniline, it shown also possible transfer functionalized polyanilines. electrode Pt shows activity toward methanol oxidation while ferricyanide quasireversible behavior Au. simple fast, works air without complex environmental conditions produce active different materials. It only requires pulsed high power laser, presently available low cost, substrata as source. this way seems general straightforward build technological devices based and/or including for direct fuel cells sensors.

参考文章(39)
Norman B. Colthup, Lawrence H. Daly, Stephen E. Wiberley, Introduction to Infrared and Raman Spectroscopy ,(1964)
Fumitaka Mafuné, Jun-ya Kohno, Yoshihiro Takeda, Tamotsu Kondow, Formation of Stable Platinum Nanoparticles by Laser Ablation in Water Journal of Physical Chemistry B. ,vol. 107, pp. 4218- 4223 ,(2003) , 10.1021/JP021580K
B. Raillard, L. Gouton, E. Ramos-Moore, S. Grandthyll, F. Müller, F. Mücklich, Ablation effects of femtosecond laser functionalization on steel surfaces Surface & Coatings Technology. ,vol. 207, pp. 102- 109 ,(2012) , 10.1016/J.SURFCOAT.2012.06.023
Natalia V. Blinova, Jaroslav Stejskal, Miroslava Trchová, Gordana Ćirić-Marjanović, Irina Sapurina, Polymerization of Aniline on Polyaniline Membranes Journal of Physical Chemistry B. ,vol. 111, pp. 2440- 2448 ,(2007) , 10.1021/JP067370F
Keiji Kunimatsu, Takahiro Senzaki, Gabor Samjeské, Minoru Tsushima, Masatoshi Osawa, Hydrogen adsorption and hydrogen evolution reaction on a polycrystalline Pt electrode studied by surface-enhanced infrared absorption spectroscopy Electrochimica Acta. ,vol. 52, pp. 5715- 5724 ,(2007) , 10.1016/J.ELECTACTA.2006.12.007
Jaroslav Stejskal, Irina Sapurina, Polyaniline: Thin films and colloidal dispersions (IUPAC Technical Report) Pure and Applied Chemistry. ,vol. 77, pp. 815- 826 ,(2005) , 10.1351/PAC200577050815
Gustaf. Forsberg, Jerome W. O'Laughlin, Robert G. Megargle, S. R. Koirtyihann, Determination of arsenic by anodic stripping voltammetry and differential pulse anodic stripping voltammetry Analytical Chemistry. ,vol. 47, pp. 1586- 1592 ,(1975) , 10.1021/AC60359A057
Guo-Chun Li, Guo-Ran Li, Shi-Hai Ye, Xue-Ping Gao, A Polyaniline‐Coated Sulfur/Carbon Composite with an Enhanced High‐Rate Capability as a Cathode Material for Lithium/Sulfur Batteries Advanced Energy Materials. ,vol. 2, pp. 1238- 1245 ,(2012) , 10.1002/AENM.201200017
Hyuna Lim, Jong-Ho Choi, A comparative study of the polyaniline thin films produced by the cluster beam deposition and laser ablation methods. Journal of Chemical Physics. ,vol. 124, pp. 014710- 014710 ,(2006) , 10.1063/1.2141508