Construction of Fullerocyclobutene Derivatives through Copper(I)-Mediated Radical Annulation of C60Cl6 with Aryl Acetylenes
作者： Shuai Wang , Ping Yan , Hui-Ying Huang , Zhuang-Ping Zhan , Su-Yuan Xie
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摘要: Have a radical ball! Reaction of C(60)Cl(6) with aryl acetylenes through copper(I)-mediated annulation route to form fullerocyclobutene derivatives is reported. The fullerocyclobutenes are obtained in 36-53% yields and possible mechanism proposed for this novel reaction.
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