Silicon carbide particle formation from carbon black —polymethylsilsesquioxane mixtures with melt pressing
作者： Masaki NARISAWA , Hiroya YASUDA , Ryota MORI , Hiroshi MABUCHI , Kunio OKA
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摘要: Precursors for silicon carbide nano particles were prepared from carbon black and polymethylsilsesquioxane (PMSQ). Ceramization process of PMSQ was characterized as preliminary information. The 29Si NMR study indicated the existence SiC3O (or SiC4) environment even at 1073 K. chemical composition pyrolyzed SiO1.5C0.68. Carbon (CB) dispersed in a benzene solution mixture freeze-dried to obtain precursor powders. powders hot pressed 573 K making contacts between CB PMSQ. cured sheets crushed heat-treated 1838 an inert atmosphere synthesize SiC with carbothermal reduction process. conversion CB-PMSQ hybrids monitored by thermogravimetric analysis. influence size content blacks on rates resulting particle morphology investigated.
sci-hub.se 参考文章(35)
N. Takamura, K. Taguchi, T. Gunji, Y. Abe, Preparation of Silicon Oxycarbide Ceramic Films by Pyrolysis of Polymethyl- and Polyvinylsilsesquioxanes Journal of Sol-Gel Science and Technology. ,vol. 16, pp. 227- 234 ,(1999) , 10.1023/A:1008765103113
Young-Wook Kim, Shin-Han Kim, Xiang Xu, Cheong-Ho Choi, Chul B. Park, Hai-Doo Kim, Fabrication of porous preceramic polymers using carbon dioxide Journal of Materials Science Letters. ,vol. 21, pp. 1667- 1669 ,(2002) , 10.1023/A:1020820608722
F.I. Hurwitz, M.A.B. Meador, Tailoring Silicon Oxycarbide Glasses for Oxidative Stability Journal of Sol-Gel Science and Technology. ,vol. 14, pp. 75- 86 ,(1999) , 10.1023/A:1008727914900
Charles W. Lewis, The pyrolysis of dimethylpolysitloxanes. II Journal of Polymer Science. ,vol. 37, pp. 425- 429 ,(1959) , 10.1002/POL.1959.1203713212
G Camino, S.M Lomakin, M Lazzari, Polydimethylsiloxane thermal degradation Part 1. Kinetic aspects Polymer. ,vol. 42, pp. 2395- 2402 ,(2001) , 10.1016/S0032-3861(00)00652-2
Manabu Fukushima, Eiichi Yasuda, Yoshiyuki Nakamura, Masao Shimizu, Yoshikazu Teranishi, L. M. Manocha, Yasuhiro Tanabe, Oxidation Behavior of Si Nb C O Ceramics Prepared by the Pyrolysis of Methyltriethoxysilane Based Organic-Inorganic Hybrid Gel Journal of Sol-Gel Science and Technology. ,vol. 34, pp. 15- 21 ,(2005) , 10.1007/S10971-005-1258-8
Kanichi Kamiya, Toshinobu Yoko, Katsuhisa Tanaka, Manabu Takeuchi, Thermal evolution of gels derived from CH3Si(OC2H5)3 by the sol-gel method Journal of Non-crystalline Solids. ,vol. 121, pp. 182- 187 ,(1990) , 10.1016/0022-3093(90)90128-9
Dušan Galusek, Jaroslav Sedláček, Peter Švančárek, Ralf Riedel, Raphaelle Satet, Michael Hoffmann, The influence of post-sintering HIP on the microstructure, hardness, and indentation fracture toughness of polymer-derived Al2O3–SiC nanocomposites Journal of The European Ceramic Society. ,vol. 27, pp. 1237- 1245 ,(2007) , 10.1016/J.JEURCERAMSOC.2006.04.028
V. M. Kevorkijan, M. Komac, D. Kolar, Low-temperature synthesis of sinterable SiC powders by carbothermic reduction of colloidal SiO2 Journal of Materials Science. ,vol. 27, pp. 2705- 2712 ,(1992) , 10.1007/BF00540693
Verena Liebau, Ralf Hauser, Ralf Riedel, Amorphous SiBCO ceramics derived from novel polymeric precursors Comptes Rendus Chimie. ,vol. 7, pp. 463- 469 ,(2004) , 10.1016/J.CRCI.2003.11.012