Acid mine drainage at Mount Morgan, Queensland (Australia): Experimental simulation and geochemical modelling of buffering reactions.

作者: Massimo Gasparon , Pilario Costagliola , Marco Benvenuti , Tony Jong , Amanda Smedley

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摘要: The Mount Morgan mine in Central Queensland, Australia, is a heavily impacted site with over 100 million tonnes of sulphide-rich waste rock accumulated during more than century gold and copper mining. Concern the potential dispersal acid drainage (AMD) into surrounding environment prompted construction water treatment plant 2006. In this study we performed some column leaching experiments developed geochemical model to simulate generation AMD reactions between lime [CaO], buffering agent used plant. Our results show that although use effective reducing acidity contaminant levels water, extremely large amounts metal-rich sludge will be generated, precipitation gypsum [CaSO4·2H2O] following reaction likely cause problems associated pipelines. process itself may have negative consequences on chemical stability waste: reduction lead dissolution jarosite [KFe3(SO4)2(OH)6], stable phase tailings under current pH conditions, release contained metals system. We demonstrate relatively simple models can predict very accurately outcomes treatment/remediation strategies, but only if geochemistry geology are well known.

参考文章(15)
R. Ciccu, M. Ghiani, A. Serci, S. Fadda, R. Peretti, A. Zucca, Heavy metal immobilization in the mining-contaminated soils using various industrial wastes Minerals Engineering. ,vol. 16, pp. 187- 192 ,(2003) , 10.1016/S0892-6875(03)00003-7
Steven A Banwart, Maria E Malmström, Hydrochemical modelling for preliminary assessment of minewater pollution Journal of Geochemical Exploration. ,vol. 74, pp. 73- 97 ,(2001) , 10.1016/S0375-6742(01)00176-5
A. Concas, C. Ardau, A. Cristini, P. Zuddas, G. Cao, Mobility of heavy metals from tailings to stream waters in a mining activity contaminated site. Chemosphere. ,vol. 63, pp. 244- 253 ,(2006) , 10.1016/J.CHEMOSPHERE.2005.08.024
Jasna Jurjovec, Carol J. Ptacek, David W. Blowes, Acid neutralization mechanisms and metal release in mine tailings: a laboratory column experiment Geochimica et Cosmochimica Acta. ,vol. 66, pp. 1511- 1523 ,(2002) , 10.1016/S0016-7037(01)00874-2
Maria E. Malmström, Magdalena Gleisner, Roger B. Herbert, Element discharge from pyritic mine tailings at limited oxygen availability in column experiments Applied Geochemistry. ,vol. 21, pp. 184- 202 ,(2006) , 10.1016/J.APGEOCHEM.2005.09.006
Connie G. Romano, K. Ulrich Mayer, David R. Jones, David A. Ellerbroek, David W. Blowes, Effectiveness of various cover scenarios on the rate of sulfide oxidation of mine tailings Journal of Hydrology. ,vol. 271, pp. 171- 187 ,(2003) , 10.1016/S0022-1694(02)00348-7
Charles A Cravotta Iii, Mary Kay Trahan, Limestone drains to increase pH and remove dissolved metals from acidic mine drainage Applied Geochemistry. ,vol. 14, pp. 581- 606 ,(1999) , 10.1016/S0883-2927(98)00066-3