Wavelength despersive spectroscopy analysis at high spectral resolution: application to the study of Mo/Si multilayers

作者: Philippe Jonnard , Hélène Maury , Jean-Michel André

DOI: 10.1002/XRS.940

关键词:

摘要: We show that x-ray emission spectroscopy (XES) induced by electrons, analyzed at high spectral resolution a WDS Johann-type spectrometer, is powerful technique to characterize in nondestructive way the interlayers Mo/Si multilayers. The analysis performed using IRIS (Instrument de Recherche sur les Interfaces et Surfaces) apparatus equipped with curved crystal. Within those experimental conditions E/∇E about 2000 1800-1900 eV photon energy range. Because of evolution shape Si Kβ band (3p-1s transition) as function chemical environment atoms easily evidenced. study series multilayers, where thickness layers 2 nm and Mo 1, 2, 3 or 4 nm. It clearly appears from within multilayers different amorphous (a-Si), which should be observed if no diffusion process takes place interfaces. By comparing a-Si molybdenum silicides simple model, we deduce composition interlayers. Their deduced estimated 0.4 ± 0.1 0.8 0.2 depending on samples.

参考文章(13)
Y. CAUCHOIS, C. BONNELLE, 3 – x-Ray Diffraction Spectrometry Experimental Approaches and Applications. ,vol. 2, pp. 83- 121 ,(1975) , 10.1016/B978-0-12-196902-8.50009-7
Mau Hsiung Chen, Bernd Crasemann, Atomic inner-shell processes ,(1975)
H. Maury, P. Jonnard, J.-M. André, J. Gautier, M. Roulliay, F. Bridou, F. Delmotte, M.-F. Ravet, A. Jérome, P. Holliger, Non-destructive X-ray study of the interphases in Mo/Si and Mo/B4C/Si/B4C multilayers Thin Solid Films. ,vol. 514, pp. 278- 286 ,(2006) , 10.1016/J.TSF.2006.02.073
C. Bonnelle, F. Vergand, P. Jonnard, J.‐M. André, P. F. Staub, P. Avila, P. Chargelègue, M.‐F. Fontaine, D. Laporte, P. Paquier, A. Ringuenet, B. Rodriguez, Instrument for research on interfaces and surfaces Review of Scientific Instruments. ,vol. 65, pp. 3466- 3471 ,(1994) , 10.1063/1.1144524
E. Z. Kurmaev, V. R. Galakhov, S. N. Shamin, Studies of solid interfaces using soft X-ray emission spectroscopy Critical Reviews in Solid State and Materials Sciences. ,vol. 23, pp. 65- 203 ,(1998) , 10.1080/10408439891324176
J.L. CAMPBELL, TIBOR PAPP, WIDTHS OF THE ATOMIC K–N7 LEVELS Atomic Data and Nuclear Data Tables. ,vol. 77, pp. 1- 56 ,(2001) , 10.1006/ADND.2000.0848
M. Iwami, Structural study of buried interface using soft X-ray emission spectroscopy Applied Surface Science. ,vol. 113114, pp. 377- 383 ,(1997) , 10.1016/S0169-4332(96)00958-0
C. Streli, G. Pepponi, P. Wobrauschek, C. Jokubonis, G. Falkenberg, G. Zaray, A new SR‐TXRF vacuum chamber for ultra‐trace analysis at HASYLAB, Beamline L X-Ray Spectrometry. ,vol. 34, pp. 451- 455 ,(2005) , 10.1002/XRS.861
P. Jonnard, C. Bonnelle, A. Bosseboeuf, K. Danaie, E. Beauprez, Investigation of an Mo/SiO2 interface by electron-induced x-ray emission spectroscopy Surface and Interface Analysis. ,vol. 29, pp. 255- 259 ,(2000) , 10.1002/(SICI)1096-9918(200004)29:4<255::AID-SIA736>3.0.CO;2-D