Influence of compositional variation on the optical and morphological properties of Gesbnd Sbsbnd Se films for optoelectronics application

作者: N. Dulgheru , M. Gartner , M. Anastasescu , M. Stoica , M. Nicolescu

DOI: 10.1016/J.INFRARED.2018.08.008

关键词:

摘要: Abstract Thin films of GexSb40-xSe60 (x = 15, 20, 25, 27, 32 and 35 at.%) were deposited on quartz by vacuum thermal evaporation the pre-synthesized parental glasses powders. By spectroscopic ellipsometry complex refractive index values are determined in 0.20–33 μm spectral range. The optical band gap single oscillator energies established as a function Ge content average coordination number Z. In (0.85–3.5) μm range possess about 80% transmission. Infrared ellipsometric Raman studies identified Se homopolar bonds, oxygen hydrogen related impurity bonds heteropolar Sb chemical bonds. Neutron- X-ray Diffraction data coupled with Reverse Monte Carlo simulations support results reproducing cell units cross-linked Atomic force microscopic imaging confirmed smooth surfaces low RMS roughness (

参考文章(32)
Z.G. Ivanova, V. Pamukchieva, M. Vlček, On the structural phase transformations in GexSb40−xSe60 glasses Journal of Non-Crystalline Solids. ,vol. 293-295, pp. 580- 585 ,(2001) , 10.1016/S0022-3093(01)00842-0
V. Pamukchieva, A. Szekeres, E. Savova, E. Vlaikova, Compositional dependence of the optical parameters of GexSb40−xSe60 glasses Journal of Non-crystalline Solids. ,vol. 242, pp. 110- 114 ,(1998) , 10.1016/S0022-3093(98)00794-7
David J. Whitehouse, Handbook of Surface Metrology ,(1994)
Sunanda Sharda, Neha Sharma, Pankaj Sharma, Vineet Sharma, Finger prints of chemical bonds in Sb–Se–Ge and Sb–Se–Ge–In glasses: A Far-IR study Journal of Non-crystalline Solids. ,vol. 362, pp. 136- 139 ,(2013) , 10.1016/J.JNONCRYSOL.2012.10.035
A. Ganjoo, H. Jain, S. Khalid, C. G. Pantano, Structural modification of Ge–Se amorphous films with the addition of Sb Philosophical Magazine Letters. ,vol. 85, pp. 503- 512 ,(2005) , 10.1080/09500830500318841
Yu Chen, Tiefeng Xu, Xiang Shen, Rongping Wang, Shuangfei Zong, Shixun Dai, Qiuhua Nie, Optical and structure properties of amorphous Ge–Sb–Se films for ultrafast all-optical signal processing Journal of Alloys and Compounds. ,vol. 580, pp. 578- 583 ,(2013) , 10.1016/J.JALLCOM.2013.07.165
Sang-Yeol Shin, J. M. Choi, Juhee Seo, Hyung-Woo Ahn, Yong Gyu Choi, Byung-ki Cheong, Suyoun Lee, The effect of doping Sb on the electronic structure and the device characteristics of Ovonic Threshold Switches based on Ge-Se Scientific Reports. ,vol. 4, pp. 7099- 7099 ,(2015) , 10.1038/SREP07099