Morphological effect of MoS2 nanoparticles on catalytic oxidation and vacuum lubrication

作者: Kun Hong Hu , Xian Guo Hu , Xiao Jun Sun

DOI: 10.1016/J.APSUSC.2009.10.098

关键词: High activityLubricationCatalysisComposite materialMaterials sciencePolyoxymethyleneNanoparticleHydrogen atmosphereChemical engineeringCatalytic oxidationDegradation (geology)

摘要: Abstract The closed layered MoS 2 nano-balls and the opened nano-slices were prepared by decomposing 3 in hydrogen atmosphere. obtained nanoparticles respectively used as catalysts for S 2− oxidation into SO 4 lubricating fillers polyoxymethylene (POM) plastic. Only basal surface could be found nano-balls, which represented very low catalytic efficiency . However, of both rim-edge showed excellent properties. Moreover, it was shown that improve self-lubrication POM plastic vacuum. led to obvious degradation POM, implying is not a proper additive POM. high activity catalyzing degrading ascribed their small sizes partly wedge-like shapes, considerable increase rim sites. weak catalysis lubrication resulted from its structure chemical inertness.

参考文章(26)
Manish Chhowalla, Gehan A. J. Amaratunga, Thin films of fullerene-like MoS2 nanoparticles with ultra-low friction and wear Nature. ,vol. 407, pp. 164- 167 ,(2000) , 10.1038/35025020
L. Rapoport, Yu. Bilik, Y. Feldman, M. Homyonfer, S. R. Cohen, R. Tenne, Hollow nanoparticles of WS2 as potential solid-state lubricants Nature. ,vol. 387, pp. 791- 793 ,(1997) , 10.1038/42910
L. Margulis, G. Salitra, R. Tenne, M. Talianker, NESTED FULLERENE-LIKE STRUCTURES Nature. ,vol. 365, pp. 113- 114 ,(1993) , 10.1038/365113B0
M. Soto-Puente, M. Del Valle, Eric Flores-Aquino, M. Avalos-Borja, S. Fuentes, J. Cruz-Reyes, Synthesis, characterization and cyclohexene hydrogenation activity of high surface area molybdenum disulfide catalysts Catalysis Letters. ,vol. 113, pp. 170- 175 ,(2007) , 10.1007/S10562-007-9030-Z
B MIREMADI, Aluminum inclusions and precipitates in restacked exfoliated MoS2 Journal of Catalysis. ,vol. 112, pp. 418- 426 ,(1988) , 10.1016/0021-9517(88)90156-X
William S. Millman, Koh-Ichi Segawa, Dale Smrz, W.Keith Hall, A comparison of the surface chemistry and catalytic properties of reduced vs sulfided molybdena-alumina catalysts Polyhedron. ,vol. 5, pp. 169- 177 ,(1986) , 10.1016/S0277-5387(00)84903-7
M. Daage, R.R. Chianelli, Structure-Function Relations in Molybdenum Sulfide Catalysts: The "Rim-Edge" Model Journal of Catalysis. ,vol. 149, pp. 414- 427 ,(1994) , 10.1006/JCAT.1994.1308
B MIREMADI, High activity catalyst from exfoliated MoS2 Journal of Catalysis. ,vol. 103, pp. 334- 345 ,(1987) , 10.1016/0021-9517(87)90125-4
V. Lavayen, N. Mirabal, C. O’Dwyer, M.A. Santa Ana, E. Benavente, C.M. Sotomayor Torres, G. González, The formation of nanotubes and nanocoils of molybdenum disulphide Applied Surface Science. ,vol. 253, pp. 5185- 5190 ,(2007) , 10.1016/J.APSUSC.2006.12.019