作者: W N Asaad , E H S Burhop
DOI: 10.1088/0370-1328/71/3/310
关键词: Relativistic quantum chemistry 、 Interpretation (model theory) 、 Allowance (engineering) 、 Atomic physics 、 Auger 、 Position (vector) 、 Spectrum (functional analysis) 、 Coupling 、 Atomic number 、 Chemistry
摘要: The fine structure of the K Auger spectrum is discussed and positions intensities K-LL K-LM lines calculated for different values Z using a non-relativistic theory assuming intermediate coupling between two inner shell vacancies atom in final states. In regions atomic number usual six-line expected on basis j-j modified into nine-line relative intensity various varies markedly with Z. effect inter-configuration terms also discussed. observed position can be understood when reasonable allowance made relativistic effects but interpretation rather meagre experimental data less clear, although there qualitative agreement theoretical predictions.