Electroless gold deposition on silicon(100) wafer based on a seed layer of silver

作者: F. Jing , H. Tong , L. Kong , C. Wang

DOI: 10.1007/S00339-003-2236-Z

关键词: X-ray photoelectron spectroscopyMicrostructureTransition metalWaferMorphology (linguistics)SiliconDeposition (law)Layer (electronics)Analytical chemistryChemistry

摘要: This article describes a method of electroless gold deposition on Si(100) wafer having silver surface as seed layer. The layer was firstly deposited onto the an etched in acidic solution 0.005 mol/L AgNO3+0.06 mol/LHF. is performed by immersing Ag-activated bath with composition 1.27×10-3 mol/L  [AuCl4]-+2.00×10-2 mol/L  NaH2PO2+8.32×10-2 mol/L NH2CH2CH2NH2 (pH = 9.0–9.5). temperature 50–70 °C. morphology and film were characterized atomic force microscopy (AFM) X-ray photoelectron spectroscopy (XPS).

参考文章(12)
M. Kato, J. Sato, H. Otani, T. Homma, Y. Okinaka, T. Osaka, O. Yoshioka, Substrate (Ni)-catalyzed electroless gold deposition from a noncyanide bath containing thiosulfate and sulfite. I. Reaction mechanism Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1448502
Yosi Shacham-Diamand, Alexandra Inberg, Yelena Sverdlov, Nathan Croitoru, Electroless Silver and Silver with Tungsten Thin Films for Microelectronics and Microelectromechanical System Applications Journal of The Electrochemical Society. ,vol. 147, pp. 3345- 3349 ,(2000) , 10.1149/1.1393904
Gopal Raghavan, Chien Chiang, Paul B. Anders, Sing-Mo Tzeng, Reynaldo Villasol, Gang Bai, Mark Bohr, David B. Fraser, Diffusion of copper through dielectric films under bias temperature stress Thin Solid Films. ,vol. 262, pp. 168- 176 ,(1995) , 10.1016/0040-6090(95)05839-7
T. Osaka, T. Misato, J. Sato, H. Akiya, T. Homma, M. Kato, Y. Okinaka, O. Yoshioka, Evaluation of Substrate (Ni)‐Catalyzed Electroless Gold Plating Process Journal of The Electrochemical Society. ,vol. 147, pp. 1059- 1064 ,(2000) , 10.1149/1.1393313
L. Magagnin, R. Maboudian, C. Carraro, Selective Deposition of Thin Copper Films onto Silicon with Improved Adhesion Electrochemical and Solid State Letters. ,vol. 4, ,(2001) , 10.1149/1.1344280
S. Warren, A. Reitzle, A. Kazimirov, J.C. Ziegler, O. Bunk, L.X. Cao, F.U. Renner, D.M. Kolb, M.J. Bedzyk, J. Zegenhagen, A structure study of the electroless deposition of Au on Si():H Surface Science. ,vol. 496, pp. 287- 298 ,(2002) , 10.1016/S0039-6028(01)01589-8
Valery M. Dubin, Yosi Shacham‐Diamand, Bin Zhao, P. K. Vasudev, Chiu H. Ting, Selective and Blanket Electroless Copper Deposition for Ultralarge Scale Integration Journal of The Electrochemical Society. ,vol. 144, pp. 898- 908 ,(1997) , 10.1149/1.1837505
A. Inberg, L. Zhu, G. Hirschberg, A. Gladkikh, N. Croitoru, Y. Shacham-Diamand, E. Gileadi, Characterization of the Initial Growth Stages of Electroless Ag(W) Films Deposited on Si(100) Journal of The Electrochemical Society. ,vol. 148, ,(2001) , 10.1149/1.1415549
A. Kohn, M. Eizenberg, Y. Shacham-Diamand, Y. Sverdlov, Characterization of electroless deposited Co(W,P) thin films for encapsulation of copper metallization Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 302, pp. 18- 25 ,(2001) , 10.1016/S0921-5093(00)01348-4
Sang Woo Lim, Renee T. Mo, Piero A. Pianetta, Christopher E. D. Chidsey, Effect of Silicon Surface Termination on Copper Deposition in Deionized Water Journal of The Electrochemical Society. ,vol. 148, ,(2001) , 10.1149/1.1344534