Degradation of Y2SiO5:Ce phosphor powders

作者: E. Coetsee , J.J. Terblans , H.C. Swart

DOI: 10.1016/J.JLUMIN.2006.05.005

关键词: CathodoluminescenceSurface layerX-ray photoelectron spectroscopyPhosphorMaterials scienceField electron emissionAnalytical chemistryImpuritySpectroscopyAuger electron spectroscopy

摘要: Abstract The degradation of the cathodoluminescence (CL) intensity cerium-doped yttrium silicate (Y2SiO5:Ce) phosphor powders was investigated for possible application in low voltage field emission displays (FEDs). Auger electron spectroscopy (AES), X-ray photoelectron (XPS) and CL were used to monitor changes surface chemical composition luminous efficiency commercially available Y2SiO5:Ce powders. is consistent with a well-known electron-stimulated reaction (ESSCR) model. It shown XPS that stimulated led formation luminescent silicon dioxide (SiO2) layer on powder. also indicated Ce concentration increased during process CeO2 CeH3 part process. first decreased until about 300 C cm−2 then due an extra peak arising at wavelength 650 nm.

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