A phosphorus‐containing diamine for flame‐retardant, high‐functionality epoxy resins. I. Synthesis, reactivity, and thermal degradation properties
作者： Weichang Liu , Russell J. Varley , George P. Simon
DOI: 10.1002/APP.20145
关键词: Polymer chemistry 、 Epoxy 、 Thermogravimetric analysis 、 Fire retardant 、 Materials science 、 Fourier transform infrared spectroscopy 、 Diamine 、 Differential scanning calorimetry 、 Chemical engineering 、 Curing (chemistry) 、 Phosphine oxide
摘要: A phosphorus-containing amine, bis(4-aminophenoxy)phenyl phosphine oxide (BAPP), suitable for curing epoxy resins with improved fire performance was synthesized and characterized Fourier transform infrared spectroscopy nuclear magnetic resonance. The reactivity of the amino group evaluated by differential scanning calorimetry epoxy–amine mixture proton resonance unit. With BAPP as a agent, range high-functionality, aerospace were cured, dynamic kinetic parameters calculated from Kissinger's Ozawa's models compared those more widely used amines. thermal degradation properties studied thermogravimetric analysis, activation energy calculated, multistep process observed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2093–2100,
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