Rhodamine based effective chemosensor for Chromium(III) and their application in live cell imaging

作者: Omprakash Sunnapu , Niranjan G. Kotla , Balaji Maddiboyina , Gyati Shilakari Asthana , Jeyabalan Shanmugapriya

DOI: 10.1016/J.SNB.2017.02.152

关键词:

摘要: Abstract A novel easily available off-on fluorescent and colorimetric probe based on rhodamine was synthesized. It showed selective sensitive recognition toward Cr 3+ in aqueous medium, with no significant interference of other competitive metal ions. The observed photophysical changes is due to the operation if internal charge transfer after addition Cr(III) ions probe. Density functional calculations (DFT) supported UV–vis absorption fluorescence emission changes. Furthermore, has been utilized for imaging HeLa cells under physiological conditions.

参考文章(55)
Jerome O Nriagu, Evert Nieboer, None, Chromium in the natural and human environments Wiley. ,(1988)
Xiaofeng Bao, Qiansheng Cao, Xuemei Nie, Yumei Zhou, Renlong Ye, Baojing Zhou, Jing Zhu, Design and synthesis of a novel chromium(III) selective fluorescent chemosensor bearing a thiodiacetamide moiety and two rhodamine B fluorophores Sensors and Actuators B-chemical. ,vol. 221, pp. 930- 939 ,(2015) , 10.1016/J.SNB.2015.07.060
Adel M. Zayed, Norman Terry, Chromium in the environment: factors affecting biological remediation Plant and Soil. ,vol. 249, pp. 139- 156 ,(2003) , 10.1023/A:1022504826342
Bernard Valeur, Mário Nuno Berberan-Santos, Molecular fluorescence : principles and applications Wiley-VCH. ,(2012) , 10.1002/9783527650002
K. Muthu Vengaian, C. Denzil Britto, Gandhi Sivaraman, Karuppannan Sekar, Subramanian Singaravadivel, Phenothiazine based sensor for naked-eye detection and bioimaging of Hg(II) and F− ions RSC Advances. ,vol. 5, pp. 94903- 94908 ,(2015) , 10.1039/C5RA19341A
Gandhi Sivaraman, Thangaraj Anand, Duraisamy Chellappa, None, A Fluorescence Switch for the Detection of Nitric Oxide and Histidine and Its Application in Live Cell Imaging ChemPlusChem. ,vol. 79, pp. 1761- 1766 ,(2014) , 10.1002/CPLU.201402217
Jia-Ni Wang, Qiong Qi, Lei Zhang, Shun-Hua Li, None, Turn-On Luminescent Sensing of Metal Cations via Quencher Displacement: Rational Design of a Highly Selective Chemosensor for Chromium(III) Inorganic Chemistry. ,vol. 51, pp. 13103- 13107 ,(2012) , 10.1021/IC3009267