Direct observations of ion-implanted xenon marker layers in anodic barrier films on aluminium

作者: K. Shimizu , G.E. Thompson , G.C. Wood , Y. Xu

DOI: 10.1016/0040-6090(82)90054-2

关键词:

摘要: Abstract Transmission electron microscopy of ultramicrotomed sections an aluminium substrate and the attached anodic film has been employed to reveal clearly implanted xenon marker layer within film. The position can be determined directly relatively precisely, without need for any indirect analytical techniques. However, depending on whether atoms are initially into metal or a preformed thin film, variation in resultant behaviour is observed. A normal uniform barrier- type formation observed when case implantation metal, more heavily flawed less current-efficient growth over area, accompanied by copious gas evolution. In latter case, transmission stripped reveals flaws as lighter finely textured spots with diameters up about 0.2 μm population density 1.5 × 10 13 m -2 . Anomalous also distribution metal. Thus, future work concerned relative mobilities migrating species contributing growth, necessary.

参考文章(10)
J. P. S. Pringle, Transport Numbers of Metal and Oxygen during the Anodic Oxidation of Tantalum Journal of The Electrochemical Society. ,vol. 120, pp. 398- 407 ,(1973) , 10.1149/1.2403466
G. E. J. Beckmann, The Growth of Silicon Carbide from Molten Silicon Journal of The Electrochemical Society. ,vol. 110, pp. 84- 86 ,(1963) , 10.1149/1.2425678
G. J. Thomas, W. Bauer, Carbide formation on Nb surfaces during high−temperature H irradiation Journal of Vacuum Science and Technology. ,vol. 12, pp. 490- 495 ,(1975) , 10.1116/1.568570
G. E. Thompson, K. Shimizu, G. C. Wood, Observation of flaws in anodic films on aluminium Nature. ,vol. 286, pp. 471- 472 ,(1980) , 10.1038/286471A0
J. A. Davies, B. Domeij, J. P. S. Pringle, F. Brown, The Migration of Metal and Oxygen during Anodic Film Formation Journal of The Electrochemical Society. ,vol. 112, pp. 675- 680 ,(1965) , 10.1149/1.2423662
K. Nisancioglu, H. Holtan, Measurement of the critical pitting potential of aluminium Corrosion Science. ,vol. 18, pp. 835- 849 ,(1978) , 10.1016/0010-938X(78)90019-7
R.C. Furneaux, G.E. Thompson, G.C. Wood, The application of ultramicrotomy to the electronoptical examination of surface films on aluminium Corrosion Science. ,vol. 18, pp. 853- 881 ,(1978) , 10.1016/0010-938X(78)90009-4
J. A. Davies, B. Domeij, The Use of α-Spectroscopy for Studying Anodic Oxidation Journal of The Electrochemical Society. ,vol. 110, pp. 849- 852 ,(1963) , 10.1149/1.2425885
J. P. Thomas, M. Fallavier, P. Spender, E. Francois, The Behavior of Implanted Xenon When Used as a Marker during the Anodic Oxidation of Aluminum Evidence for an Explanation of a Dose‐Dependant Splitting Effect Journal of The Electrochemical Society. ,vol. 127, pp. 585- 590 ,(1980) , 10.1149/1.2129716