Architectured Bi2S3 nanoflowers: photoenhanced field emission study

作者: Sambhaji S. Warule , Ranjit V. Kashid , Deodatta R. Shinde , Nilima S. Chaudhari , Bharat B. Kale

DOI: 10.1007/S11051-012-0889-2

关键词:

摘要: In the present investigation, we demonstrate a facile hydrothermal/solvothermal route to fabricate elegant Bi2S3 nanoflowers in large scale with highly oriented (001) surfaces. The synthesis was observed radically determine overall morphology of resultant product. Under hydrothermal conditions (12 h), formation flowers on nickel foil composed self-assembled tapered nanorods were obtained. Whereas after prolonged reaction time (24 h), ultra long micro belts observed. Interestingly, architectured obtained by solvothermal are seen be self assembled and it also that duration influences their shape, size, areal density. Finding such unique nanostructures arose exemplify prominent photoenhanced field emission upon visible light illumination, which is attributed photoconductivity Bi2S3. It noteworthy studies reveal low turn-on ~1.04 V/μm, required draw an current density ~0.1 μA/cm2, found lower than earlier reports. average stable over 3 h. addition, behavior single flower (pasted tungsten microtip) has been investigated. high sensitivity fast response switching indicate as promising candidate for micro/nano-optoelectronic devices. .

参考文章(29)
R. Viswanatha, D. D. Sarma, Growth of Nanocrystals in Solution John Wiley & Sons, Ltd. pp. 139- 170 ,(2007) , 10.1002/9783527611362.CH4
Yujiang Xiao, Huaqiang Cao, Kaiyu Liu, Sichun Zhang, Victoria Chernow, The synthesis of superhydrophobic Bi(2)S(3) complex nanostructures. Nanotechnology. ,vol. 21, pp. 145601- 145601 ,(2010) , 10.1088/0957-4484/21/14/145601
Tianyou Zhai, Liang Li, Ying Ma, Meiyong Liao, Xi Wang, Xiaosheng Fang, Jiannian Yao, Yoshio Bando, Dmitri Golberg, One-dimensional inorganic nanostructures: synthesis, field-emission and photodetection. Chemical Society Reviews. ,vol. 40, pp. 2986- 3004 ,(2011) , 10.1039/C0CS00126K
Asif Ali Tahir, Muhammad Ali Ehsan, Muhammad Mazhar, K. G. Upul Wijayantha, Matthias Zeller, A. D. Hunter, Photoelectrochemical and photoresponsive properties of Bi2S3 nanotube and nanoparticle thin films Chemistry of Materials. ,vol. 22, pp. 5084- 5092 ,(2010) , 10.1021/CM101642B
Padmakar G. Chavan, Satish S. Badadhe, Imtiaz S. Mulla, Mahendra A. More, Dilip S. Joag, Synthesis of single crystalline CdS nanocombs and their application in photo-sensitive field emission switches Nanoscale. ,vol. 3, pp. 1078- 1083 ,(2011) , 10.1039/C0NR00659A
Ashok B. Bhise, Dattatray J. Late, Bhaskar R. Sathe, Mahendra A. More, Imtiaz S. Mulla, Vijayamohanan K. Pillai, Dilip S. Joag, Field emission investigation of single Fe-doped SnO2 wire Solid State Sciences. ,vol. 11, pp. 1114- 1117 ,(2009) , 10.1016/J.SOLIDSTATESCIENCES.2009.02.011
Anuja Datta, Padmakar G Chavan, Farid Jamali Sheini, Mahendra A More, Dilip S Joag, Amitava Patra, None, Growth, Optical, and Field Emission Properties of Aligned CdS Nanowires Crystal Growth & Design. ,vol. 9, pp. 4157- 4162 ,(2009) , 10.1021/CG900388V
Ashok B. Bhise, Dattatray J. Late, Pravin S. Walke, Mahendra A. More, Vijayamohanan K. Pillai, Imtiaz S. Mulla, Dilip S. Joag, Sb-doped SnO2 wire: Highly stable field emitter Journal of Crystal Growth. ,vol. 307, pp. 87- 91 ,(2007) , 10.1016/J.JCRYSGRO.2007.06.017
Tong Wu, Xinggui Zhou, Hua Zhang, Xinhua Zhong, Bi2S3 nanostructures: A new photocatalyst Nano Research. ,vol. 3, pp. 379- 386 ,(2010) , 10.1007/S12274-010-1042-0
Haifeng Bao, Xiaoqiang Cui, Chang Ming Li, Ye Gan, Jun Zhang, Jun Guo, Photoswitchable Semiconductor Bismuth Sulfide (Bi2S3) Nanowires and Their Self-Supported Nanowire Arrays Journal of Physical Chemistry C. ,vol. 111, pp. 12279- 12283 ,(2007) , 10.1021/JP073504T