Multi‐ion‐beam reactive sputter deposition of ferroelectric Pb(Zr,Ti)O3 thin films

作者: S. B. Krupanidhi , H. Hu , V. Kumar

DOI: 10.1063/1.350719

关键词: SputteringAnalytical chemistryLead zirconate titanateIon beamFerroelectricityThin filmCrystallizationSputter depositionMaterials scienceMineralogyIon implantation

摘要: A multi‐ion‐beam reactive sputter (MIBERS) deposition technique was devised to grow ferroelectric lead zirconate titanate (PZT) thin films of different compositions (Zr/Ti ratios 50/50 and 56/44) from individual metal targets Pb, Zr, Ti. This offers a highly controllable process allowing excellent uniformity in composition thickness over large area (7.5 cm diameter) on reproducible basis. The PZT were deposited variety unheated substrates annealed by two techniques, rapid thermal annealing conventional furnace annealing. Both techniques induced perovskite phase with good morphology. effect the excess Pb content observed terms crystallization It seen that presence tends enhance formation but degrades orientation. low‐energy oxygen ion beam employed modify f...

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