Core-Shell Structure of Acceptor-Rich, Coarse Barium Titanate Grains

作者: Seok-Hyun Yoon , Je-Hun Lee , Doh-Yeon Kim , Nong M. Hwang

DOI: 10.1111/J.1151-2916.2002.TB00593.X

关键词:

摘要: Heavily doped barium titanate (BaTiO3) powders, one with a donor-rich and the other an acceptor-rich composition, were prepared. After sintering, specimen exhibited fine-grained microstructure but significant grain growth occurred in specimen. A stable dielectric behavior was observed only over temperature range studied. However, both specimens, undoped core region several hundred nanometers size detected. The core-shell structure appeared to be maintained BaTiO3 under conventional sintering conditions.

参考文章(18)
Walter Heywang, Structural engineering of ferroelectrics Ferroelectrics. ,vol. 49, pp. 3- 14 ,(1983) , 10.1080/00150198308244662
D.F.K. Hennings, B.S. Schreinemacher, Temperature-stable dielectric materials in the system BaTiO3-Nb2O5-Co3O4 Journal of the European Ceramic Society. ,vol. 14, pp. 463- 471 ,(1994) , 10.1016/0955-2219(94)90085-X
Sea-Fue Wang, Thomas C. K. Yang, Wayne Huebner, Jinn P. Chu, Liquid-phase sintering and chemical inhomogeneity in the BaTiO3–BaCO3–LiF system Journal of Materials Research. ,vol. 15, pp. 407- 416 ,(2000) , 10.1557/JMR.2000.0064
HELEN M. CHAN, MARTIN R HARMER, DONALD ML SMYTH, Compensating Defects in Highly Donor-Doped BaTiO3 Journal of the American Ceramic Society. ,vol. 69, pp. 507- 510 ,(1986) , 10.1111/J.1151-2916.1986.TB07453.X
Joo-Hwan Han, Doh-Yeon Kim, Determination of three-dimensional grain size distribution by linear intercept measurement Acta Materialia. ,vol. 46, pp. 2021- 2028 ,(1998) , 10.1016/S1359-6454(97)00442-4
Hirokazu Chazono, Hiroshi Kishi, Sintering Characteristics in BaTiO3–Nb2O5–Co3O4 Ternary System: I, Electrical Properties and Microstructure Journal of the American Ceramic Society. ,vol. 82, pp. 2689- 2697 ,(2004) , 10.1111/J.1151-2916.1999.TB02143.X
Kevin W. Kirby, Barry A. Wechsler, Phase relations in the Barium Titanate—Titanium Oxide System Journal of the American Ceramic Society. ,vol. 74, pp. 1841- 1847 ,(1991) , 10.1111/J.1151-2916.1991.TB07797.X
MIHA DROFENIK, Oxygen Partial Pressure and Grain Growth in Donor-Doped BaTiO3 Journal of the American Ceramic Society. ,vol. 70, pp. 311- 314 ,(1987) , 10.1111/J.1151-2916.1987.TB04999.X
Hong-Yang Lu, Jong-Shing Bow, Wen-How Deng, Core-Shell Structures in ZrO2-Modified BaTiO3 Ceramic Journal of the American Ceramic Society. ,vol. 73, pp. 3562- 3568 ,(1990) , 10.1111/J.1151-2916.1990.TB04258.X
Lorenz S. Sigl, Hans-Joachim Kleebe, Core/Rim Structure of Liquid‐Phase‐Sintered Silicon Carbide Journal of the American Ceramic Society. ,vol. 76, pp. 773- 776 ,(1993) , 10.1111/J.1151-2916.1993.TB03677.X