Hydrolysis and polycondensation of acid-catalyzed Phenyltriethoxysilane (PhTES)

作者: Minoru Kuniyoshi , Masahide Takahashi , Yomei Tokuda , Toshinobu Yoko

DOI: 10.1007/S10971-006-7465-0

关键词:

摘要: The effects of acid catalyst, water content and reaction temperature on the hydrolysis polycondensation phenyltriethoxysilane (PhTES) were studied using 29Si NMR spectroscopy. sol catalyzed by hydrochloric showed simultaneous progress polycondensation. In addition, rate was almost independent temperature. On other hand, in PhTES-derived mixed with an excess amount acetic as a catalyst proceeded after completion hydrolysis. acid-catalyzed system, degree largely depends

参考文章(24)
Chenghong Li, Thomas Glass, Garth L. Wilkes, NMR Studies of Sol-Gel Derived Hybrid Materials Based on Triethoxysilylated Diethylenetriamine and Tetramethoxysilane Journal of Inorganic and Organometallic Polymers and Materials. ,vol. 9, pp. 79- 106 ,(1999) , 10.1023/A:1021435232746
C. Jeffrey Brinker, George W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing ,(1990)
Ulrich Schubert, Nicola Hüsing, Synthesis of Inorganic Materials Wiley-VCH. ,(2000)
F. I. Hurwitz, L. Hyatt, J. Gorecki, L. D'Amore, Silsesquioxanes as Precursors to Ceramic Composites 11th Annual Conference on Composites and Advanced Ceramic Materials: Ceramic Engineering and Science Proceedings, Volume 8, Issue 7/8. pp. 732- 743 ,(1987) , 10.1002/9780470320402.CH29
C.J. Brinker, M.S. Harrington, Sol-gel derived antireflective coatings for silicon Solar Energy Materials. ,vol. 5, pp. 159- 172 ,(1981) , 10.1016/0165-1633(81)90027-7
G. D. West, G. G. Diamond, N. Dajda, M. E. Smith, M. H. Lewis, Structural characterisation of organosiloxane membranes British Ceramic Transactions. ,vol. 102, pp. 93- 98 ,(2003) , 10.1179/096797803225004918
C. Y. Wang, Z. X. Shen, J. Z. Zheng, Thermal Cure Study of a Low-k Methyl Silsesquioxane for Intermetal Dielectric Application by FT-IR Spectroscopy Applied Spectroscopy. ,vol. 54, pp. 209- 213 ,(2000) , 10.1366/0003702001949410
Keiji Kobayashi, Low polarization and low temperature reflow of inorganic borophosphosilicate glasses formed from organic sources Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 98, pp. 181- 183 ,(2003) , 10.1016/S0921-5107(02)00311-2
Robert W. Schwartz, Chemical Solution Deposition of Perovskite Thin Films Chemistry of Materials. ,vol. 9, pp. 2325- 2340 ,(1997) , 10.1021/CM970286F
Atsunori Matsuda, Teruyuki Sasaki, Koichi Hasegawa, Masahiro Tatsumisago, Tsutomu Minami, Thermal Softening Behavior and Application to Transparent Thick Films of Poly(benzylsilsesquioxane) Particles Prepared by the Sol–Gel Process Journal of the American Ceramic Society. ,vol. 84, pp. 775- 780 ,(2001) , 10.1111/J.1151-2916.2001.TB00740.X